THE STUDY OF VOLUME DEFORMATIONS OF MAGNESIA STONE AND THEIR DEPENDENCE ON ACTIVITY OF APPLIED BINDERS
Keywords:
volume deformations, magnesium hydroxide, magnesium oxide, magnesia stone, phase composition, activity of the binderAbstract
The interrelation of deformations of magnesium-chlorate binder in the initial period of solidification with activity of initial powder of magnesium oxide, which is determined by parameters of stoving of the initial raw material, is studied in the article. Magnesium binders obtained on the basis of chemically pure magnesium hydroxide were taken for the research which included an analysis of phase composition with the use of the derivatographic analysis. Stoving of the raw material was conducted at various temperature regimes with the goal to obtain binders of various activities. Typical composition of hydrate phases in a solidified magnesia stone, obtained on the basis of binders of various rates of activity, is determined. The influence of activity of magnesium binder on the process of volume deformations occurrence in magnesia stone and its susceptibility to cracking is revealed.
References
Biliuski H., Matcovic B., Mazuranic C., Zumic T. [Structure and Formation of Magnesium Oxychloride Sorel Cements]. J. Amer. Ceram. Soc., 1984, vol. 67, no. 2, pp. 266-269.
Nanazashvili I.H. Stroitel'nye materialy iz drevesno-cementnoj kompozicii [Building Materials from Wood- Cement Composition]. Moscow, Strojizdat Publ., 1990, 470 p.
Jan'shina A.P. [Features of Roasting Magnesium Hydroxide from Brine]. Ogneupory [Refractories], 1960, no. 11, pp. 505-515 (in Russ.).
Matcovic B., Popovic S., Rogic V., Zunic T. [The Mechanism of the Hydration of Magnum Oxide]. J. Amer. Ceram. Soc., 1977, vol. 60, no 11, pp. 504-507.
Chumak V.G. [A Novelty that is More than 100 Years Old]. Stroitel'nye materialy [Building Materials], 2003, no. 9, pp. 10-11 (in Russ.).
Rogic V., Matkovic B. [Phsesin Magnesium Oxychloride Cement (in Croatia)]. Cement (Zagreb), 1972, vol.16, no. 2, pp. 61-69.
Sims C. [Caustic Magnesia. Industry Follows a Declining Herd]. Industrial Minerals, 1987, no 2, pp. 43-48.
Bergman G.A., Vyrodov I.P. [On the Question of Curing Cements Hlormagnezialnyh]. Journal of Applied Chemistry, 1958, no. 1, pp. 19-24 (in Russ.).
Bergman G.A., Vyrodov I.P. [On the Question of Curing Cements Hlormagnezialnyh. (Report II)]. Journal of Applied Chemistry, 1959, no. 3, pp. 504-509 (in Russ.).
Vorob'ev V.A., Kolokol'nikov V.S. Proizvodstvo mineral'nyh vjazhushhih [Production of Mineral Binders], Moscow, Gosstrojizdat Publ., 1960, 304 p.
Vyrodov I.P. [About The Formation of the Structure of Magnesia Cements]. Journal of Applied Chemi¬stry, 1960, no. 11, pp. 2399-2404 (in Russ.).





