SYNTHESIS OF COPOLYMERS OF METHYL METHACRYLATE AND BUTYLVINYL ETHER IN THE PRESENCE OF THE SYSTEM TRIBUTYLBORON– 2,5-DI-TERT-BUTYL-P-BENZOQUINONE

Юлия Леонидовна Кузнецова, Наталья Александровна Абрамова, Дмитрий Владимирович Лудин

Аннотация


The synthesis of copolymers of methyl methacrylate and butylvinyl ether using the system tributylboron–2,5-di-tert-butil-p-benzoquinone has been carried out. This system does not influence the reactivity ratios of these monomers. Predominantly, the terminal unit of butylvinyl ether reacts with p-quinone. Controlled radical polymerization is realized along with the conventional process.

Ключевые слова


methyl methacrylate; butylvinyl ether; azobisisobutyronitrile; tri-n-butylboron; 2,5-di-tert-butyl-p-benzoquinone; UVspectroscopy; controlled radical polymerization

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Литература


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