CHANGING THE MICROHARDNESS OF ABSOLUTE SOLID ALLOYS WITH THEIR IRRADIATION OF A GAS-METALLIC BEAK OF ARGON AND ZIRCONIUM IONS

Authors

  • V. V. Akimov Siberian State Automobile and Highway University, Omsk
  • A. F. Mishurov Siberian State Automobile and Highway University, Omsk
  • D. A. Negrov Omsk State Technical University, Omsk
  • Ya. A. Sidorova Siberian State Automobile and Highway University, Omsk
  • V. Yu. Putintsev Omsk State Technical University, Omsk

Keywords:

tungsten-free, refractory compounds, microhardness, composite, implantation, ions, dose, binding phase, cermet teeth

Abstract

In this paper, we consider a method for increasing the microhardness of the surface of a tungsten carbide based on titanium carbide with a titanium nickelide (TiNi) intermetallide. It is known that the matrix in solid composite materials should exhibit the ability to randomly form during the deformation of the composite, and also to harden and wet the solid particles well, providing a strong bond over the phase boundaries and a high density during sintering. The increase in the strength properties and hardness of composite materials is achieved by improving the microstructure, eliminating defects in their structure, while improving the wetting processes of the bonding phase. It has been experimentally established that the process of irradiating the surface of polished samples with Ar+ and Zr+ ions with an energy of about 20 keV and a dose of 1017 ion/cm2 of a hard alloy leads to a significant change in the microhardness of the material due to the formation of quenching point defects that arise upon intensive heating and cooling of composite samples. As a result of the implantation of solid alloys, the structure is formed in highly nonequilibrium conditions of interaction of the surface of a non-slippery alloy with a concentrated flow of energy and matter. Therefore, this method of increasing strength and microhardness is a promising way to increase the wear resistance of disintegrator beams and cermet teeth used in road construction machines for repairing road surfaces. In addition, a change in the temperature arising upon irradiation of solid alloys of the TiC–TiNi system plays a significant role in the formation of its structure and in the change in microhardness on the surface of the samples.

References

Panin V.E., Grinyaev Yu.V., Danilov V.I. et al. Strukturnyye urovni plasticheskoy deformatsii i razrusheniya [Structural levels of plastic deformation and fracture]. Novosibirsk, Nauka, Sib. otdelenie Publ., 1990, pp. 187–201.

Grigorovich A.K. Tverdost’ i mikrotverdost’ metallov [Hardness and microhardness of metals]. Moscow, Nauka Publ., 1976, 230 p.

Akimov V.V. [Investigation of microhardness of hard alloys based on titanium carbide]. Vestnik IGTU, 2005, no. 3 (23), pp. 121–124. (in Russ.)

Akimov V.V., Mishurov A.F., Korytov M.S. at al. [Effect of heat treatment on the change in microhardness and phase composition of solid TiC–TiNi alloys]. Omskiy nauchnyy vestnik, 2006, no. 9 (46), pp. 31–33. (in Russ.)

Akimov V.V. [Mechanism of liquid-phase sintering of carbide composites TiC–TiNi]. Izvestiya vysshikh uchebnykh zavedeniy. Chernaya metallurgiya, 2006, no. 6, pp. 33–35. (in Russ.)

Brandon D., Kaplan U. Mikrostruktura materialov. Metody issledovaniya i kontrolya [Microstructure of materials. Methods of research and control]. Moscow, Tekhnosfera Publ., 2004, 384 p.

Rakovsky V.S. Spechennyye materialy v tekhnike [Sintered materials in engineering]. Moscow, Metallurgiya Publ., 1998, 263 p.

Panov V.S., Zaitsev A.A. [Solid alloys WС–Co, doped with tantalum carbide]. Poroshkovaya metallurgiya i funktsional'nye pokrytiya, 2015, no. 2, pp. 44–48. (in Russ.)

Andrievsky R.A., Spivak I.I. Prochnost’ tugoplavkikh soyedineniy i materialov na ikh osnove: spravochnik [Strength of refractory compounds and materials based on them: reference]. Chelyabinsk, Metallurgiya Publ., 1989, 368 p.

Andrievsky R.A. [Nanocomposites based on refractory compounds: the state of development and prospects]. Materialovedenie, 2006, no. 4, pp. 20–26. (in Russ.)

Rusinov P.O., Blednova Zh.N. [Structural and technological regularities in the formation of surface layers from a material with shape memory effect by high-speed gas-flame spraying]. Fizikokhimicheskie aspekty izucheniya klasterov, nanostruktur i nanomaterialov, 2014, no. 6. рр. 322–329. (in Russ.)

Kheifets M.L., Kolmakov A.G., Klimenko S.A. [Physicochemical structural analysis of the structure of materials from chemical disorder to nonequilibrium thermodynamics]. Mekhanika mashin, mekhanizmov i materialov, 2017, no. 2 (39), рр. 65–72. (in Russ.)

Klubovich V.V. Rubanik V.V. [Martensitic transformations in titanium nickelide of ion-plasma deposition of a TiN coating]. Materialy, tekhnologii, instrumenty, 2013, vol.18, no. 2, pp. 47–51. (in Russ.)

Bleicher, V.P. Krivobokov, Pashchenko O.V. Teplomassoperenos v tverdom tele pod deystviyem moshchnykh puchkov zaryazhennykh chastits [Heat and mass transfer in a solid under the action of powerful beams of charged particles]. Novosibirsk, Nauka Publ., 1999, 176 p.

Postnikov D.V. [Model of the redistribution of elements in steels when irradiated with beams of charged particles]. Omskiy nauchnyy vestnik, 2006, no. 9 (46), pp. 33–36. (in Russ.)

Gulkin A.V., Postnikov D.V., Plotnikov S.V. [Redistribution of elements during pulsed irradiation by beams of charged particles]. Proceedings of the 4th Int. scientific conf. “Radiation-thermal effects and processes in inorganic materials”, Tomsk, 2004, pp. 354. (in Russ.)

Korusenko P.M., Nesov S.N., Bolotov V.V., Povoroznyuk S.N., Pushkarev A.I., Knyazev E.V. Change in the chemical state and concentration of iron in carbon nanotubes obtained by the CVD method and subjected to pulsed ion irradiation. Physics of the Solid State, 2017, vol. 59, iss. 10, pp 2045–2052. DOI: 10.1134/s1063783417100249

Bolotov V.V., Korusenko P.M., Nesov S.N., Povoroznyuk S.N., Stenkin Yu.A. [Influence of a pulsed ion beam on the electronic structure of nitrogen atoms in multiwalled carbon nanotubes doped with nitrogen]. Omskiy nauchnyy vestnik, 2016, no. 4 (148), pp. 119–122. (in Russ.)

Nesov S.N., Korusenko P.M., Povoroznyuk S.N., Bolotov V.V. [Modified structures of the phase composition of composites using composites based on MWNT and tin oxide using powerful ion irradiation]. In the book: Chemistry under the sign of SIGMA: Research, innovation, technology. Abstracts of the V All-Russian Scientific and Youth School-Conference, 2016, р. 257. (in Russ.)

Korusenko P.M., Bolotov V.V., Nesov S.N., Povoroznyuk S.N., Khailov T.P. Сhages of the electronic structure of the autos of nitrogen in nitrogen – doped multiwalled carbon nanotubes under the influence of pulsed ion radiation. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions Materials and Atoms, 2015, vol. 358, pp. 131–135. DOI: 10.1016/j.nimb.2015.06.009

Downloads

Published

2020-11-09

Issue

Vol. 19 No. 4 (2019)

Section

Physical Metallurgy and Heat Treatment