EFFECTS OF GERMANY AND STRONTIUM ON THE MICROSTRUCTURE AND MECHANO-TECHNOLOGICAL PROPERTIES OF THE AK9M2 ALLOY
DOI:
https://doi.org/10.14529/met190106Keywords:
alloy AK9M2, strontium, germanium, mechanical properties, technological propertiesAbstract
Foundry aluminum-silicon alloy AK9M2 is widely used in the automotive industry for the casting
of castings for various purposes. This alloy during casting is modified by sodium. However,
the effect of modifying with sodium does not exceed 30–40 minutes, which requires a second operation.
Recently, more and more in the foundry industry when casting from silumin castings, aluminum
ligatures with strontium are used, which are distinguished by a long-lasting effect of preserving
the effect of modifying up to eight or more hours, and also after 2–4 melts.
In this regard, the work presents the results of a study of the effect of joint additions of germanium
and strontium on the mechanical properties of cuprous silumin of grade AK9M2, as well as
the microstructure of alloys. It is shown that the additions of strontium and germanium together provide
a high cooperativity of phase growth in the α-Al–Si eutectic, as well as the hardening of
the α-solid aluminum solution. Germanium and strontium have a modifying effect on the microstructure
of the alloy AK9M2, resulting in an increase in the mechanical properties of the alloys. In this
case, additives up to 0.1–0.3% of germanium increase the fluidity of the AK9M2 alloy by more than
1.3 times. This is accompanied by a decrease in the volume of the concentrated shrinkage shell by
10–12%. The addition of strontium favorably affects the fluidity of the alloy only when the germanium
content is about 0.1% (by mass). The positive effect of germanium on the mechanical and casting
and technological properties of the alloy AK9M2 is enhanced in the presence of strontiu
References
Mondolfo L.F. Aluminum Alloys: Structure and Properties. Butterworth-Heinemann, 1976. 982 p. DOI: 10.1016/C2013-0-04239-9
Ganiev I.N., Vakhobov A.V., Semenova O.N. [Structure and Properties of Silumin Modified with Strontium]. Sovremennyye metody proizvodstva otlivok, sposobstvuyushchiye ekonomii materialov i toplivno-energeticheskikh resursov: tez. dokl. XIII nauch.-tekhn. konf. liteyshchikov Zapadnogo Urala [Modern Methods of Casting Production, which Contribute to Saving Materials and Fuel and Energy Resources: Abstracts of XIII Scientific and Technical. Conf. Founders of the Western Urals]. Perm’. 1984, pp. 28–29. (in Russ.)
Gorokhov Yu.V., Sherkunov V.G., Konstantinov I.L. The Research Methodology of Continuous Press-Casting of Metals. Bulletin of the South Ural State University. Ser. Metallurgy, 2015, vol. 15, no. 2, pp. 82–88. (in Russ.)
Berdiev A.E., Ganiev I.N., Gulov S.S., Sangov M.M. [Kinetics of Oxidation of a Hard Alloy AK7M2 Doped with Germanium]. Proceedings of Universities. Chemistry and Chemical Technology, 2013, vol. 56, no. 3, pp. 28–30. (in Russ.)
Berdiyev A.E., Ganiev I.N., Gulov S.S. Kinetics of Oxidation of a Solid Alloy AK7M2 + 0.05 % Sr, Doped with Germanium. Russian Journal of Non-Ferrous Metals, 2014, vol. 55, iss. 5, pp. 416–418. DOI: 10.3103/S1067821214050046
Berdiyev A.E., Ganiev I.N., Gulov S.S. Siluminy, modifitsirovannyye elementami podgruppy germaniya i strontsiya [Silumin, Modified by Elements of the Subgroup of Germanium and Strontium]. Germany, Ed. House LAP LAMBERT Academic Publishing, 2011. 142 p.
Olimov N.S., Ganiev I.N., Obidov Z.R., Shirinov M.Ch. Oxidation of the Alloys of the Al-Ge System, in the Liquid State. Melt, 2015, no. 4, pp. 28–36. (in Russ.)
Ganiev I.N. Parhutik P.A., Vakhobov A.V., Kupriyanova I.Yu., Ed. K.W. Gorev. Modifitsirovaniye siluminov strontsiyem [Modification of Silumin with Strontium]. Minsk, Science and Technology, 1985. 143 p.
Ganiev I.N., Vakhobov A.V., Dzhuraev T.D., Kalyaeva V.G. [Modification of Al-Si Alloys AL-4 and AL-9]. Foundry, 1975, no. 1, pp. 33–34. (in Russ.)
Ganiev I.N., Vakhobov A.V., Semenova A.N. Effect of the Composition and Microalloying with Strontium on the Structure and Properties of Al-Si-Mg Alloys. Metal Science and Heat Treatment, 1983, vol. 25, iss. 8, pp 623–625. DOI: 10.1007/BF00741928
Ganiev I.N., Trubnyakova E.D. [Modifying Effect of Strontium on the Corrosion-Electrochemical Behavior of Silumin, in Neutral Media]. Journal of Applied Chemistry, 1986. vol. 59, no. 11, pp. 2545–2548. (in Russ.)
Vakhobov A.V., Ganiev I.N. [Strontium-Effective Modifier of Silumines]. Foundry, 2000, no. 5, p. 28. (in Russ.)
Kargopolova T.B., Mahmadulloev Kh.A., Ganiev I.N., Khakdodov M.M. [Barium – a New Modifier of Silumin]. Foundry, 2001, no. 10, pp. 6–9. (in Russ.)
Ganiev I.N., Vakhobov A.V., Khakdodov M.M., Mahmadulloev Kh.A. [Development and Introduction of New Cast Aluminum Alloys, Strontium Containing Ligatures and Modifiers into Production]. Metallurgy and Heat Treatment of Metals, 2002, no. 10, pp. 38–39. (in Russ.)
Ganiev I.N., Gulov S.S., Ganieva N.I., Davlatnazarova N.V. [Influence of Strontium and Methods of Its Introduction into the Melt on the Properties of Industrial Silumin]. Izvestiya AN Respubliki Tadzhikistan. Otd. fiz.-mat., khim., geol. i tekhn. nauk [Proceedings of the Academy of Sciences of the Republic of Tajikistan. Fiz.-Mat., Chemical., Geol. and Those. Sciences], 2007, no. 1, pp. 68–78. (in Russ.)
Gulov S.S., Ganiev I.N., Umarova T.M., Berdiev A.E. [Corrosion-Electrochemical Behavior of the AK7M2 + 0.05% Sr Alloy Doped with Germanium in a 3% NaCl Solution]. Reports of the Academy of Sciences of the Republic of Tajikistan, 2009, vol. 52, no. 6, pp. 460–464. (in Russ.)
Gudchenko A.P., Zalinova I.M. [Modification of Al-Si Alloys with Strontium]. Foundry, 1972, no. 12, pp. 30. (in Russ.)
Zalinova I.M., Gudchenko A.P., Pankovaya L.E. [Kinetics of Strontium Oxidation in a Melt]. Foundry, 1974, no. 10, pp. 20–21. (in Russ.)
Ganiev I.N., Vakhobov A.V., Juraev G.D., Valyaeva V.G. [Modification of Al-Si Alloys with Strontium]. Foundry, 1975, no. 1, pp. 33–34. (in Russ.)
Alker K. Veredelung von Al-Si Legierungen durch Natrium oder Strontium: Eine Gegenüberstellung. Geiberai – Praxis, 1972, Nr. 24, S. 434–438.
Latkowski A., Gryziecki J., Jarominek J. Wpliw obrobki cieplnej na wlasnosci mechaniczne stopu Al-Si-Mg-Cu-Ni, modifikovanego strontem. Rudy in metal niczelazne, 1976, vol. 21, no. 3, pp. 52–56.
Hess P.D., Blackman E.V. Strontium as a Modifying Agent for Hypoeutectic Aluminium-Silicon Alloys. AFS Transactions, 1975, pp. 87–90.
Barbe P.S., Erdmann-Jeshitzer K., Krug T. Anwendung der thermischen Analyse für Überwachung der Veredelungswirkung Strontium in der Legierung Ge-Al-Si 10,5. Giesserei, 1982, Bd. 69, Nr. 14, S. 393–397.
Andurshevich A.A., Lubensky M.Z. Pimenova G.P. [Modification of Aluminum-Silicon Alloys with Strontium]. Foundry, 1983, no. 10, pp. 9–11. (in Russ.)
Justi S. Investigations with the High Temperature Microscope of Aluminum-Silicon Alloys Modified with Strontium. Giessereiforschung, 1975, vol. 27, no. 4, pp. 141–143.
Kutsenok N.L., Andrushevich A.A., Ganiev I.N., Yanchuk V.N. [Technological Features of Modifying Silumin with Aluminum-Strontium Ligatures]. The Technology of the Automotive Industry, 1983, no. 8, pp. 7–10. (in Russ.)
Zalinova I.M. Gudchenko A.P. [The Influence of Strontium on the Interaction of Silumin with Gases]. Foundry, 1977, no. 1, p. 35. (in Russ.)
Semenova O.N., Ganiev I.N., Vakhobov A.V. [The Effect of Chlorine and Phosphorus Additives on the Preservation of the Effect of Modifying Strontium Containing Silumin]. Foundry, 1984, no. 6, pp. 13–14. (in Russ.)
Ganiev I.N., Vakhobov A.V., Dzhuraev T.D., Ivlev V.A. [Effect of Strontium on the Impact Strength of AK9]. Foundry, 1976, no. 2, p. 41. (in Russ.)