Study of Structural Characteristics of Ni-Zn-Co Ferrospinels

D. P. Sherstyuk, V. E. Zhivulin, A. Yu. Starikov, I. A. Solizoda, K. P. Pavlova, A. Yu. Punda, D. A. Zherebtsov, D. A. Vinnik

Abstract


Currently, in the modern scientific literature there is an increased interest in ferrites of all types. Among them, a special place is occupied by Ni-Zn ferrite with a spinel structure. It is known that the functional properties of ferrites can be significantly changed by partial or complete replacement of the cations of the initial matrix with other cations differing in magnetic moment and size. Such a change in the structure makes it possible to effectively vary the properties of ferrites, i.e. to provide "tuning" of the material for the required properties. An analysis of the literature in this direction has shown that the cobalt ion Co2+ is an effective substitute cation. In this study we are dealing with the Ni-Zn ferrites of variable composition, with the fixed content x(Co) = 0.1. The general formula is: Co0.1Zn0.9-xNixFe2O4, (where x = 0; 0.3; 0.6; 0.9). The aim of the presented work is to synthesize samples, as well as to study their density and porosity, which in turn have a direct effect on the performance properties of ceramic ferrites. The synthesis of the samples was carried out by the solid-phase reaction method, using a high-temperature furnace in an air atmosphere. Previous studies have made it possible to identify a set of optimal physicochemical conditions under which the initial charge ferritization occurs. The initial components for preparing the charge included oxides. X-ray phase analysis and X-ray structural analysis, electron microscopy and energy dispersive X-ray spectroscopy were used as research methods. As a result of X-ray phase analysis, it has been revealed that the obtained samples are monophasic and belong to spinels of the AFe2O4 type (where element A = Ni, Zn, Co). The study of the surface morphology of the samples has revealed the presence of many crystallites of various sizes, the natural faceting of which corresponds to crystallites with a cubic syngony. Investigations of the true and X-ray density of the obtained samples have been carried out. The dependence of the influence of the substitution value x(Ni) on the porosity (density), as well as on the parameters of the elementary crystal lattice, has been determined.

Keywords


modern functional materials; ceramics; ferrites; substituted ferrites; spinel ferrites; structure; solid-phase synthesis

References


Исследование особенностей состава, магнитной и кристаллической структуры гексафер-рита бария BaFe12–xTixO19 / В.В. Коровушкин, А.В. Труханов, В.Г. Костишин и др. // Физика твер-дого тела. – 2020. – Т. 62, № 5. – С. 789–798. DOI: 10.21883/FTT.2020.05.49250.622

Abu-Elsaad, N.I. Synthesis, Structural Characterization, and Magnetic Properties of Ni–Zn Nanoferrites Substituted with Different Metal Ions (Mn2+, Co2+, and Cu2+) / N.I. Abu-Elsaad, A.S. Nawara, S.A Mazen // J. Phys. Chem. Solids. – 2020. – V. 146. DOI: 10.1016/j.jpcs.2020.109620

Structural and Magnetic Studies of Nanocrystalline Ni-Zn Ferrites Synthesized by Sol-Gel Method / Y.P. Desai, S. Jamwal, S. Modiyil et al. // AIP Conf. Proc. – 2020. DOI: 10.1063/5.0016757

Exchange-Coupling Effect in Hard/Soft SrTb0.01Tm0.01Fe11.98O19/AFe2O4 (Where A = Co, Ni, Zn, Cu and Mn) Composites / N.A. Algarou, Y. Slimani, M.A. Almessiere et al. // Ceram. Int. – 2019. – Vol. 46, № 6. – P. 7089–98. DOI:10.1016/j.ceramint.2019.11.201

Synthesis, Microstruture and Electromagnetic Performance of NixZn1–xFe2O4 Ferrites with Dif-ferent Ni/Zn Ratios Prepared by a Novel Molten Salt Method / P. Yang, H. Qi, Z. Peng et al. // IOP Conf. Ser.: Mater. Sci. Eng. – 2019. DOI: 10.1088/1757-899X/678/1/012141

Influence of Chromium Substitution on Structural, Electrical, and Magnetic Properties of Ni-Zn-Cu Ferrites / G. Satyanarayana, G.N. Rao, K.V. Babu et al. // Acta Phys. Pol., A – 2020. – Vol. 138, № 3. – P. 355–63. DOI: 10.12693/APhysPolA.138.355

Investigations of Co Substitution on the Structural and Magnetic Properties of Ni-Zn Spinel Ferrite / J. Hu, Y. Ma, X. Kan et al. // J. Magn. Magn. Mater. – 2020. – V. 513. DOI:10.1016/j.jmmm.2020.167200

Structural and Magnetic Investigation of Al3+ and Cr3+ substituted Ni–Co–Cu Nanoferrites for Potential Applications / R. Jasrotia, S. Kour, P. Puri et al. // Solid State Sci. – 2020. – V. 110. DOI: 10.1016/j.solidstatesciences.2020.106445

Structural, electric and dielectric properties of Ni0.5Zn0.5FeCoO4 ferrite prepared by sol-gel Author links open overlay panel / A. Omri, E. Dhahri, B.F.O. Costa et al. // J. Magn. Magn. Mater. – 2020. – V. 499. – 166243. DOI: 10.1016/j.jmmm.2019.166243

Microstructure and Magnetic Properties of Ni-Mg-Zn-Co Ferrites / S.B. Patil, A.J. Davari, D.R. Patil et al. // Macromol. Symp. – 2020. – V. 393, № 1. – 2000179. DOI: 10.1002/masy.202000179

Estimation of Structural, Electrical, and Magnetic Variations of Mn-Ni- Zn Ferrites by Substi-tuting Rare Earth Y3+ for High-Frequency Applications / K.H. Maria, U.S. Akther, I.N. Esha et al. // J. Supercond. Novel Magn. – 2020. – Vol. 33, № 7. – 2133–2142. DOI: 10.1007/s10948-020-05471-9

Study the Physical, Electrical and Dielectric Properties of Calcium Doped Ni-Zn Ferrites / M.A.A. Nooman, M.N.I. Khan, S.D. Hossain et al. // Mod. Phys. Lett. B. – 2019. – Vol. 33, № 12. – 1950145. DOI: 10.1142/S0217984919501458

Spectroscopic Analysis and Temperature-Dependent Dielectric Properties of Bulk Ni-Zn Ce-ramics / A. Yadav, P. Choudhary, P. Saxena et al. // J. Adv. Dielectr. – 2019. – V. 9, № 2. – 1950014. DOI: 10.1142/S2010135X19500140

Agami, W.R. Effect of Neodymium Substitution on the Electric and Dielectric Properties of Mn-Ni-Zn Ferrite / W.R. Agami // Phys. B: Condensed Matter. – 2018. – Vol. 534. – P. 17–21. DOI: 10.1016/j.physb.2018.01.021

Understanding the Impacts of Al+3-Substitutions on the Enhancement of Magnetic, Dielectric and Electrical Behaviors of Ceramic Processed Nickel-Zinc Mixed Ferrites: FTIR assisted studies / T.K. Bromho, K. Ibrahim, H. Kabir // Mater. Res. Bull. – 2018. – V. 97. – P. 444–451. DOI: 10.1016/j.materresbull.2017.09.013

Синтез и структура керамики бизамещенного гексаферрита M-типа BaFe(11,5–x)Ti0,5AlxO19 / И.A. Солизода, В.Е. Живулин, Д.П. Шерстюк и др. // Вестник ЮУрГУ. Серия «Химия». – 2020. – Т. 12, № 4. – С. 110–119. DOI: 10.14529/chem200408

Correlation Between Structural, Magnetic and Dielectric Properties of Microwave Sintered Ni-Zn-Al Nanoferrites / C.S. Ega, B.R. Babu, K.V. Ramesh et al. // J. Supercond. Novel Magn. – 2019. – Vol. 32, № 11. – P. 3525–34. DOI: 10.1007/s10948-019-5097-1

The Influence of Nd Substitution in Ni–Zn Ferrites for the Improved Microwave Absorption Properties / K. Qian, Z. Yao, H. Lin et al. // Ceram. Int. – 2020. – Vol. 46, № 1. – P. 227–35. DOI: 10.1016/j.ceramint.2019.08.255

Studies of Magnetic, Mössbauer Spectroscopy, Microwave Absorption and Hyperthermia Behavior of Ni-Zn-Co-Ferrite Nanoparticles Encapsulated in Multi-Walled Carbon Nanotubes / M. Dalal, A. Das, D. Das et al. // J. Magn. Magn. Mater. – 2018. – V. 460. – P. 12–27. DOI: 10.1016/j.jmmm.2018.03.048

X-band Shielding Properties of Mg-9Li matrix Composite Containing Ni0.4Zn0.4Co0.2Fe2O4 Fab-ricated by Multi-Layer Composite Rolling / J. Wang, Y. Li, R. Wu et al. // J. Alloys Compd. – 2020. – Vol. 843. – 156053. DOI: 10.1016/j.jallcom.2020.156053

Mattei, J.-L. Magnetic and Dielectric Properties in the UHF Frequency Band of Half-Dense Ni-Zn-Co Ferrites Ceramics with Fe-excess and Fe-deficiency / J.-L. Mattei, D. Souriou, A. Chevalier // J. Magn. Magn. Mater. – 2018. – Vol. 447. – P. 9–14. DOI: 10.1016/j.jmmm.2017.09.030

Изучение влияния замещения кобальтом на структуру никель-цинкового феррита / Д.П. Шерстюк, А.Ю. Стариков, В.Е. Живулин и др. // Вестник ЮУрГУ. Серия «Металлургия». – 2020. – Т. 20, № 2. – С. 51–56. DOI: 10.14529/met200205

Синтез, структура и свойства Zn0,3Ni0,7–xCoxFe2O4 (x = 0–0,6) феррита / Д.П. Шерстюк, А.Ю. Стариков, В.Е. Живулин и др. // Вестник ЮУрГУ. Серия «Химия». – 2020. – Т. 12, № 4. – С. 92–100. DOI:10.14529/chem200406

Shannon, R.D. Revised Effective Ionic Radii and Systematic Studies of Interatomic Distances in Halides and Chalcogenides / R.D. Shannon // Scta Cryst. – 1976. – P. 751–767

Van Horn, J.D. Electronic Table of Shannon Ionic Radii / J.D. Van Horn // Electronic Table. – 2001.


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