Гибридные органо-неорганические соединения, получаемые методом золь-гель химии из органоалкоксисиланов и металлокомплексов

Владимир Викторович Семенов

Аннотация


В работе суммированы сведения об узком классе поликонденсированных систем, известных как органо-неорганические гибридные материалы, в которых частицы металлокомплексов внедрены в кремнийоксидную матрицу. Представлены частицы только одного типа – координационные соединения кобальта, хрома, неодима, эрбия и иттербия. Эти материалы получают золь-гель процессом из молекулярных предшественников, которые подвергаются неорганической полимеризации, называемой гидролитической поликонденсацией. Представлены основные сведения о золь-гель процессах. Рассмотрены типы и свойства наиболее распространенных золь-гель мономеров и олигомеров, способы получения металлосодержащих гелей, сделано общее представление о золь-гель процессах, перечислены сферы применения получаемых материалов. Синтезы силоксановых, карбонатных и карбонатно-силоксановых кобальткарбонильные гелей основаны на реакции гомомолекулярного диспропорционирования октакарбонила дикобальта под действием 3-аминопропилтриэтоксисилана, пиридина и диметилформамида. Ряд кремнийорганических аминных гелей получен из 3-аминопропилтриэтоксисилана, хлоридов кобальта(II), хрома(III) и триэтоксисилана. Из кремнийорганических аминных комплексов получены золь-гель пленки, содержащие кобальт, хром и неодим, измерены и интерпретированы их электронные спектры поглощения, показаны превращения, происходящие при абсорбции кислорода и хлористого водорода, измерены нелинейно-оптические свойства. Кремнийорганические амидофосфаты синтезированы взаимодействием 3-аминопропилтриэтоксисилана с бис(диметиламидо)хлорфосфатом и дифенилхлорфосфатом. На их основе получены комплексы эрбия и иттербия, измерены их спектры поглощения и испускания. Приведены два примера иммобилизации металлокомплексов на поверхности высокопористого гидридполисилоксана и лепидоидного силоксена.

Ключевые слова


органоалкоксисиланы; гибридные органо-неорганические соединения; золь-гель процессы; 3-аминопропилтриэтоксисилан; координационные соединения; кобальт; хром; неодим; эрбий; иттербий; кобальткарбонильные гели; гидридполисилоксан; силоксен

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DOI: http://dx.doi.org/10.14529/10.14529/chem210402

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