SYNTHESIS AND STRUCTURE OF AROXY-TETRA-P-TOLYLANTIMONY (4-MeC6H4)4SbOC6H2Br2-2,6-(t-Bu)-4

Павел Валерьевич Андреев, Владимир Викторович Шарутин, Ольга Константиновна Шарутина

Аннотация


Penta-p-tolylantimony interaction with 2,6-dibromo(4-tert-butyl)phenol has led to synthesis of the complex tetra-p-tolylantimony 2,6-dibromo(4-tert-butyl)phenoxide, whose structure has been established by X-ray diffraction. The antimony atom in the molecule (4-MeC6H4)4SbOC6H2Br2-2,6-(t-Bu)-4 has distorted trigonal-bipyramidal coordination with the aroxy group in axial position. The bond Sb-O is 2.229(2) Å, the axial angle CSbO is 176.82(10)°


Ключевые слова


tetra-p-tolylantimony 2,6-dibromo(4-tert-butyl)phenoxide; synthesis; molecular structure; X-ray analysis

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Литература


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