Batch adsorption studies for malachite green dye removal from waste water using biomass based adsorbent

Sunanda Sharma, K K Pant, D P Tiwari

Аннотация


Adsorption of malachite green dye over the adsorbents (Ad) derived from Sapindus seed hull (S) and Camelina (C) after treatment with sulphuric acid is studied. Batch adsorption study on both Ad is compared as a function of various parameters such as pH, time, initial concentration and temperature. The isotherm data is found to be best presented by Langmuir model for both adsorbents. Separation factor (RL) revealed a favorable adsorption. Further, the rate of adsorption followed pseudo-first order kinetics. The intraparticle diffusion model facilitates to understand mass transfer in adsorption of dye molecules. Thermodynamic analysis on both Ad revealed the spontaneity of the phenomena at higher temperature. The comparative study illustrated higher adsorption capacity of CAd in comparison to SAd.

Ключевые слова


Adsorption; malachite green; Sapindus; Camelina

Полный текст:

PDF PDF (English)

Литература


Chowdhury S., Mishra R., Saha P., Kushwaha P. Adsorption Thermodynamics, Kinetics and Isosteric Heat of Adsorption of Malachite Green onto Chemically Modified Rice Husk. Desalin., 2011, vol. 265, pp. 159–168. DOI: 10.1016/j.desal.2010.07.047.

Gou Y., Yang S., Fu W., Qi J., Li R., Wang Z. Adsoprtion of Malachite Green on Micro- and Mesoporous Rice Husk-based Active Carbon. Dye. Pigment, 2003, vol. 56, pp. 219–229. DOI: 10.1016/S0143-7208(02)00160-2.

Gupta V.K., Mittal A., Krishnan L., Gajbe V. Adsorption Kinetics and Column Operations for the Removal and Recovery of Malachite Green from Wastewater Using Bottom Ash. Sep. Purif. Technol, 2004, vol. 40, pp. 87–96. DOI:10.1016/j.seppur.2004.01.008.

Hameed B.H., El-Khaiary M.I. Kinetics and Equilibrium Studies of Malachite Green Adsorption on Rice Straw-derived Char. J. Hazard. Mater, 2008, vol. 153, pp. 701–708. DOI: 10.1016/j.jhazmat.2007.09.019.

Mittal A., Krishnan L., Gupta V.K. Removal and Recovery of Malachite Green from Wastewater Using an Agricultural Waste Material, De-oiled Soya. Sep. Purif. Technol, 2005, vol. 43, pp. 125–133. DOI: 10.1016/j.seppur.2004.10.010.

Rahman I.A., Saad B., Shaidan S., Sya Rizal E.S. Adsorption Characteristics of Malachite Green on Activated Carbon Derived from Rice Husks Produced by Chemical-thermal Process. Bioresour. Technol, 2005, vol. 96, pp. 1578–1583. DOI: 10.1016/j.biortech.2004.12.015.

Santhi T., Manonmani S., Smitha T. Removal of Malachite Green from Aqueous Solution by Activated Carbon Prepared from the Epicarp of Ricinus communis by Adsorptionl. J. Hazard. Mater, 2010, vol. 179, pp. 178–186. DOI: 10.1016/j.jhazmat.2010.02.076.

Tian Y., Liu P., Wang X., Lin H. Adsorption of Malachite Green from Aqueous Solutions onto Ordered Mesoporous Carbons.Chem. Eng. J, 2011, vol. 171, pp. 1263–1269. DOI:10.1016/j.cej.2011.05.040.

Mittal A. Adsorption Kinetics of Removal of a Toxic Dye, Malachite Green, from Wastewater by Using Hen Feathers. J. Hazard. Mater, 2006, vol. 133, pp. 196–202. DOI: 10.1016/j.jhazmat.2005.10.017.

Ahmad M.A., Alrozi R. Removal of Malachite Green Dye from Aqueous Solution Using Rambutan Peel-based Activated Carbon: Equilibrium, Kinetic and Thermodynamic Studies. Chem. Eng. J, 2011, vol. 171, pp. 510–516. DOI: 10.1016/j.cej.2011.04.018.

Ahmad R., Kumar R. Adsorption Studies of Hazardous Malachite Green onto Treated Ginger Waste. J. Environ. Manage, 2010, vol. 91, pp. 1032–1038. DOI: 10.1016/j.jenvman.2009.12.016.

Akmil-Başar C., Önal Y., Kiliçer T., Eren D. Adsorptions of High Concentration Malachite Green by Two Activated Carbons Having Different Porous Structures. J. Hazard. Mater, 2005, vol. 127, pp. 73–80. DOI: 10.1016/j.jhazmat.2005.06.025

Kadirvelu K., Kavipriya M., Karthika C., Radhika M., Vennilamani N., Pattabhi S. Utilization of Various Agricultural Wastes for Activated Carbon Preparation and Application for the Removal of Dyes and Metal Ions from Aqueous Solutions. Bioresour. Technol, 2003, vol. 87, pp. 129–132. DOI: 10.1016/S0960-8524(02)00201-8.

Crini G. Non-conventional Low-cost Adsorbents for Dye Removal: A review. Bioresour. Technol, 2006, vol. 97, pp. 1061–1085. DOI: 10.1016/j.biortech.2005.05.001.

Bekçi Z., Özveri C., Seki Y., Yurdakoç K.Sorption of Malachite Green on Chitosan Bead. J. Hazard. Mater, 2008, vol. 154, pp. 254–261. DOI: 10.1016/j.jhazmat.2007.10.021.

Bekçi Z., Seki Y., Cavas L. Removal of Malachite Green by Using an Invasive Marine Alga Caulerpa racemosa Var. cylindracea. J. Hazard. Mater, 2009, vol. 161, pp. 1454–1460. DOI: 10.1016/j.jhazmat.2008.04.125.

Hameed B.H., El-Khaiary M.I. Batch Removal of Malachite Green from Aqueous Solutions by Adsorption on Oil Palm Trunk Fibre: Equilibrium isotherms and Kinetic Studies. J. Hazard. Mater, 2008, vol. 154, pp. 237–244. DOI: 10.1016/j.jhazmat.2007.10.017.

Khattri S.D., Singh M.K. Removal of Malachite Green from Dye Wastewater Using Neem Sawdust by Adsorption. J. Hazard. Mater, 2009, vol. 167, pp. 1089–1094. DOI: 10.1016/j.jhazmat.2009.01.101.

Nethaji S., Sivasamy A., Thennarasu G., Saravanan S. Adsorption of Malachite Green Dye onto Activated Carbon Derived from Borassus Aethiopum flower Biomass. J. Hazard. Mater, 2010, vol. 181, pp. 271–280. DOI: 10.1016/j.jhazmat.2010.05.008.

Önal Y., Akmil-Başar C., Eren D., Sarici-Özdemir Ç.̧, Depci T. Adsorption Kinetics of Malachite Green onto Activated Carbon Prepared from Tunçbilek Lignite. J. Hazard. Mater, 2006, vol. 128, pp. 150–157. DOI: 10.1016/j.jhazmat.2005.07.055.

Wang X.S., Zhou Y., Jiang Y., Sun C. The Removal of Basic Dyes from Aqueous Solutions Using Agricultural By-products. J. Hazard. Mater, 2008, vol. 157, pp. 374–385. DOI: 10.1016/j.jhazmat.2008.01.004.

Zhang J., J. Li J., J. Zhang J., Jing Y. Adsorption of Malachite Green from Aqueous Solution onto Carbon Prepared from Arundo Donax Root. J. Hazard. Mater, 2008, vol. 150, pp. 774–782. DOI: 10.1016/j.jhazmat.2007.05.036.

Hameed B.H., El-Khaiary M.I. Equilibrium, Kinetics and Mechanism of Malachite Green Adsorption on Activated Carbon Prepared from Bamboo by K2CO3 Activation and Subsequent Gasification with CO2. J. Hazard. Mater, 2008, vol. 157, pp. 344–351. DOI: 10.1016/j.jhazmat.2007.12.105.

Sharon M., Soga T., Afre R., Sathiyamoorthy D., Dasgupta K., Bhardwaj S., Sharon M., Jaybhaye S. Hydrogen Storage by Carbon Materials Synthesized from Oil Seeds and Fibrous Plant Materials. Int. J. of Hy. En, 2007, vol. 32, pp. 4238−4249.DOI: 10.1016/j.ijhydene.2007.05.038.

Uğurlu M., Kula I., Karaoğlu M.H., Arslan Y. Removal of Ni(II) Ions from Aqueous Solutions Using Activated-carbon Prepared from Olive Stone by ZnCl2 Activation. Environ. Prog. Sustain Energy, 2009, vol. 28, pp. 547–557. DOI: 10.1002/ep.10358.

Tan I.A.W., Ahmad A.L., Hameed B.H. Adsorption Isotherms, Kinetics, Thermodynamics and Desorption Studies of 2,4,6-Trichlorophenol on Oil Palm Empty Fruit Bunch-based Activated Carbon. J. Hazard. Mater, 2009, vol. 164, pp. 473–482. DOI:10.1016/j.jhazmat.2008.08.025.

Chowdhury S., Saha P. Sea Shell Powder as a New Adsorbent to Remove Basic Green 4 (Malachite Green) from Aqueous Solutions: Equilibrium, Kinetic and Thermodynamic Studies. Chem. Eng. J, 2010, vol. 164, pp. 168–177. DOI: 10.1016/j.cej.2010.08.050.

Ghaedi M., Ansari A., Habibi M.H., Asghari A.R. Removal of Malachite Green from Aqueous Solution by Zinc Oxide Nanoparticle Loaded on Activated Carbon: Kinetics and Isotherm Study. J. Ind. Eng. Chem, 2014, vol. 20, pp. 17–28. DOI: 10.1016/j.jiec.2013.04.031.

Tang H., Zhou W., Zhang L. Adsorption Isotherms and Kinetics Studies of Malachite Green on Chitin Hydrogels. J. Hazard. Mater, 2012, vol. 209–210, pp. 218–225. DOI: 10.1016/j.jhazmat.2012.01.010.

Baek M.H., Ijagbemi C.O., O S.J., Kim D.S. Removal of Malachite Green from Aqueous Solution Using Degreased Coffee Bean. J. Hazard. Mater, 2010, vol. 176, pp. 820–828. DOI: 10.1016/j.jhazmat.2009.11.110.

Namasivayam C., Kavitha D. Removal of Congo Red from Water by Adsorption onto Activated Carbon Prepared from Coir Pith, an Agricultural Solid Waste. Dyes and Pigm., 2002, vol. 54, pp. 47−58. DOI: 10.1016/S0143-7208(02)00025-6.

Ahmad M.A., Alrozi R. Removal of Malachite Green Dye from Aqueous Solution Using Rambutn peel-based Activated Carbon: Equilibrium, Kinetic and Thermodynamic Studies. Chem. Engg. J., 2011, vol. 171, pp. 510−516. DOI: 10.1016/j.cej.2011.04.018.


Ссылки

  • На текущий момент ссылки отсутствуют.