Строение органических и элементоорганических соединений

Владимир Викторович Шарутин

Аннотация


Методом рентгеноструктурного анализа (РСА) определено строение восьми органических и элементоорганических соединений. РСА соединений проводили на автоматическом четырехкружном дифрактометре D8 Quest Bruker (МоКα-излучение,
λ = 0,71073 Å, графитовый монохроматор) при 293 К. Cоединение [Ph3PMe] [RuCl4(DMSO)2] (1) P-1, a = 8,4181(3), b = 8,9389(3), c = 11,1396(4) Å, a = 69,754(1),
β = 81,913(2), g = 64,491(1) град., V = 709,75(4) Å3, Z = 1. [Ph3PC6H4CH2CN] Cl × CHCl3 (2),
P 21/n, a = 9,846(6) Å, b = 15,782(14) Å, c = 15,111(10) Å, a = 90, β = 91,027(18), g = 90 град., V = 2348(3) Å3, Z = 4. Ph4SbOC6H4(NO2-4) (3), P-1, a = 11,101(6), b = 12,684(6),
c = 19,359(9) Å, a = 80,973(17), β = 80,17(2), g = 72,31(3) град., V = 2543(2) Å3, Z = 4.
(4-BrC6H4)3Sb (4), P-1, a = 6,273(12), b = 12,83(2), c = 13,26(3) Å, a = 78,67(8),
β = 84,33(9), g = 80,81(7) град., V = 1031(3) Å3, Z = 2. Ph4PBr·H2O (5), P-1, a = 10,025(10), b = 10,676(10), c = 10,706(13) Å, a = 77,56(4), β = 71,80(4), g = 83,26(3) град., V = 1061(2) Å3, Z = 2. [4-MeOC6H4]3Sb (6), R-3, a = 13,27(3), b = 13,27(3), c = 19,24(7) Å, a = 77,56(4), β = 90, g = 120 град., V = 2935(20) Å3, Z = 6. [Ph3PCH2C6H4CN-4]Cl, P 21/n, a = 9,456(6),
b = 14,733(9), c = 16,271(9) Å, a = 90, β = 104,83(2), g = 90 град., V = 2191(2) Å3, Z = 4. [Ph3PCH2OH]Сl, P 21/c, a = 8,888(9), b = 17,795(19), c = 11,278(12) Å, a = 90, β = 99,52(4),
g = 90 град., V = 1759(3) Å3, Z = 4.

Ключевые слова


строение; органическое; элементорганическое соединение; рентгеноструктурный анализ

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