Use of Boric Acid Solutions in Organic Liquids as Boron-Containing Fertilizers. Influence of Root Treatment on Yield and Chemical Composition of Winter and Spring Wheat

Authors

  • N. A. Kodochilova Nizhny Novgorod Research Agricultural Institute – Branch of “Federal Agricultural Research Center of the North-East named N.V. Rudnitskogo”
  • A. O. Ivanenkova Nizhny Novgorod Research Agricultural Institute – Branch of “Federal Agricultural Research Center of the North-East named N.V. Rudnitskogo”
  • T. S. Buzynina Nizhny Novgorod Research Agricultural Institute – Branch of “Federal Agricultural Research Center of the North-East named N.V. Rudnitskogo”
  • V. V. Semenov .A. Razuvaev Institute of Organometallic Chemistry of the RAS
  • B. I. Petrov .A. Razuvaev Institute of Organometallic Chemistry of the RAS
  • N. M. Lazarev .A. Razuvaev Institute of Organometallic Chemistry of the RAS

Keywords:

boric acid, monoethanolamine, diethanolamine, triethanolamine, glycerol, ethylene glycol, morpholine, wheat, yield, winter hardiness, crop structure

Abstract

The conditions for dissolution of boric acid in monoethanolamine, diethanolamine, triethanolamine, glycerol, ethylene glycol and morpholine were selected, which made it possible to obtain low-viscosity solutions with a concentration that was many times higher than the maximum attainable concentration in water and did not produce precipitates during storage. The resulting solutions were used as microfertilizers for foliar feeding and seed treatment of winter (Moskovskaya 56) and spring (Zlata) wheat. The use of boron as a microelement contributed to the preservation of a larger number of living plants of winter wheat during the wintering period, and, consequently, the better winter hardiness of the crop. The maximum value of the winter wheat yield was obtained when the seeds were treated with monoethanolamine borate. The highest values of the indicators of the yield structure belonged to the grain of winter wheat against the background of the seed treatment with a chelated form of boron: for the number and weight of grains when monoethanolamine borate was used; for the length of the ear when glycerol borate was used. The treatment of the Moskovskaya 56 wheat seeds with the microelement led to an increase in the amount of nitrogen in the grain relative to the control by 7–11 %. The highest values belonged to the variants including the treatment of seeds with the traditional form of the element (aqueous solution of boric acid), as well as the treatment with monoethanolamine borate. The maximum increase in the yield of the Zlata spring wheat was observed on feeding with a solution of boric acid in glycerol: 3.26 t / ha (2.1 times higher than on feeding with the traditional form of the microelement). Boron as a microelement contributed to an increase in the structural parameters of spring wheat plants in all forms. The greatest positive effect was noted from the action of glycerol borate, where the difference to the control variant was 2.4 times for the number of grains in an ear to the control, and their weight was 2.7 times. After the use of boron the spring wheat gluten was characterized as good (quality group I).

Author Biographies

N. A. Kodochilova, Nizhny Novgorod Research Agricultural Institute – Branch of “Federal Agricultural Research Center of the North-East named N.V. Rudnitskogo”

кандидат биологических наук, ведущий научный сотрудник

A. O. Ivanenkova, Nizhny Novgorod Research Agricultural Institute – Branch of “Federal Agricultural Research Center of the North-East named N.V. Rudnitskogo”

кандидат биологических наук, старший научный сотрудник

T. S. Buzynina, Nizhny Novgorod Research Agricultural Institute – Branch of “Federal Agricultural Research Center of the North-East named N.V. Rudnitskogo”

младший научный сотрудник

V. V. Semenov, .A. Razuvaev Institute of Organometallic Chemistry of the RAS

химических наук, ведущий научный сотрудник

B. I. Petrov, .A. Razuvaev Institute of Organometallic Chemistry of the RAS

доктор технических наук, заместитель директора

N. M. Lazarev, .A. Razuvaev Institute of Organometallic Chemistry of the RAS

кандидат химических наук, научный сотрудник

References

Рабинович, В.А. Краткий химический справочник / В.А. Рабинович, З.Я. Хавин. – Л.: Химия, 1991. – 432 с.

Несмеянов, А.Н. Методы элементоорганической химии / А.Н. Несмеянов, Р.А. Соколик // Бор, алюминий, галлий, индий, таллий. – М.: Наука, 1964. – 499 с.

Кешан, А.Д. Синтез боратов в водном растворе и их исследование / А.Д. Кешан. – Рига: Изд-во АН Латв. ССР, 1955. – 240 с.

Исследование механизма реакции между борной кислотой и моноэтаноламином в водной среде / В.Г. Скворцов, А.К. Молодкин, О.В. Петрова и др. // Журн. неорган. химии. – 1980. – Т. 25, № 7. – С. 1964–1969.

Исследование комплексобразования между борной кислотой и диэтаноламином / В.Г. Скворцов, А.К. Молодкин, Н.С. Родионов, Н.Р. Цеханская // Журн. неорган. химии – 1981. – Т. 26, № 5. – С. 1389 – 1393.

Zhou, L. Borate coupling agent and its preparation method / L. Zhou, H. Ruan, W. Zhu et al. // Faming Zhuanli Shenqing (2012), CN 102532602A20120704.

Synthesis and Tribological Properties of s- and p-Free Borate Esters with Different Chain Lengths / G. Yang, Z. Zhang, G. Li et al. // J. Tribology. – 2011. – V. 133, № 2. – P. 021801/1–021801/7. DOI: 10.1115/1.4003304.

Formation of Boron Nitride and Boron Carbide by Pyrolysis of Condensation Products of Boric Acid and Ethanolamines / H. Wada, K. Nojima, K. Kuroda, C. Kato // Yogyo Kyokaishi. – 1987. – V. 95, № 1. – P. 130–134.

Кремнийборсодержащий глицерогидрогель с ранозаживляющей, регенерирующей и антимикробной активностью / О.Н. Чупахин, Т.Г. Хонина, Н.В. Кунгуров и др. // Изв. АН. Сер. хим. – 2017, № 3. – С. 558–563.

Структурные особенности полимерных кремнийглицеролатных гелей / Е.Ю. Ларченко, В.В. Пермикин, А.П. Сафронов, Т.Г. Хонина // Изв. АН. Сер. хим. – 2017, № 8. – С. 1478–1482.

Novel (Glycerol)borate – Based Ionic Liquids: an Experimental and Theoretical Study / C. Chiappe, F. Signori, G. Valentini et al. // J. Phys. Chem. B. – 2010. – V. 114, № 15. – P. 5082–5088. DOI: 10.1021/jp100809x

Zhou, P. Application Study of Boric Acid Glycerin Polyester in Electrolytic Capacitors / P. Zhou, R. Liu, L. Long // Huaxue Gongchengshi. – 2013. – V. 27, № 1. – P. 49–51.

Tahara, N. Effect of Addition of Tartaric Acid on Synthesis of Boron Carbide Powder from Condensed Boric Acid Glycerin Product / N. Tahara, M. Kakiage, I. Yanase, H. Kobayashi // J. Alloys and Compounds. – 2013. – V. 573. – P. 58–64. DOI: 10.1016/j.jallcom,2013.03.255

Kakiage, M. Low-temperature Synthesis of Boron Carbide Powder from Condensed Boric Acid Glycerin Product / M. Kakiage, N. Tahara, I. Yanase, H. Kobayashi // Mater. Lett. – 2011. – V. 65, № 12. – P. 1839–1841. DOI: 10/1016j.matlet.2011.03.046.

Wada, H. Preparation of Boron Nitride Boron Carbide Ceramics by Pyrolysis of Boric Acid Glycerin Condensation Product / H. Wada, K. Kuroda, C. Kato // Mat. Sci. Res. – 1986. – V. 20. – P. 179–185.

Treatment of Plywood to Reduce Smoke / Y. Ogawa, H. Hisada, N. Shiina, H. Okutani // Jpn. Kokai Tokkyo Koho. 1975. JP 50089511 A 19750718.

Yonezawa, T. Electrolytes for Electrolytic Capacitors / T. Yonezawa // Jpn. Kokai Tokkyo Koho. 2002. JP 2002175945 A 20020621.

Richmond, J.M. Textile Softening Composition / J.M. Richmond // U.S. 1983. US 4399044 A 19830816.

Ellis, J.M.H. Hydraulic Fluids / J.M.H. Ellis // Ger. Offen. 1975. DE 2525403 A1 19751218.

Physicochemical Study of the Boric Acid – Ethylene Glycol System / V.G. Kalacheva, E. Svarcs, V.G. Ben'kovskii, I.D. Leonov // Latvijas PSR Zinatnu Akad. Vestis. Kim. Ser. – 1970, № 6. – P. 679–683.

Kalacheva, V.G. Reaction of Boric Acid with Ethylene Glycol / V.G. Kalacheva, V.G. Ben'kovskii, E. Svarcs // Latvijas PSR Zinatnu Akad. Vestis. Kim. Ser. – 1969, № 2. – P. 149–151.

Convenient and Fast Synthesis of Boratrane in Water Medium / Yu.I. Bolgova1, G.A. Kuznetsova, O.M. Trofimova, M.G. Voronkov // Chem. Heterocycl. Comp. – 2013. – V. 49, № 8. – P. 1246–1248. DOI: 10.1007/s10593-013-1370-6.

Лядов, А.С. Биоглицерин – альтернативное сырье для основного органического синтеза / А.С. Лядов, С.Н. Хаджиев // Журн. прикл. химии. – 2017. – Т. 90, № 11. – С. 1417–1428. DOI: 10.1134/S1070427217110015.

Титова, В.И. Справочное пособие по агрохимии и экологии / В.И. Титова, В.Г. Бусоргин, О.Д. Шафронов и др. – Н. Новгород: НГСХА, 2005. – 70 с.

Published

2021-05-13