Синтез и строение дицианоаурата цианометилтрифенилфосфония и дицианоаргентата  бензилтрифенилфосфония

M. A. Popkova; V. V. Sharutin

Authors

M. A. Popkova South Ural State University
V. V. Sharutin South Ural State University

Keywords:

synthesis, dicyanoaurate, dicyanoargentate, complex, structure, X-ray diffraction analysis

Abstract

The interaction of potassium dicyanoaurate and dicyanoargentate with organyltriphenylphosphonium chlorides in water leads to complexes [PH₃PH₂CN]⁺[Au(CN)₂]^– (1) and [PH₃PH₂PH]⁺[Ag (CN)₂] (2), which and structurally characterized. The phosphorus atoms in organyltriphenylphosphonium cations have a distorted tetrahedral coordination: the CPC angles equal 106.21(17)–111.02(16)° (1), 106.13(7)–111.06(7)° (2), The P-C bonds are 1.782(3)–1.818(3) Å (1) and 1.7985(16)–1.8064(16) Å (2). In the almost linear [Au(CN)₂]⁻ anions the CAuC angles are 178.10(19)° (1), the Au-C distances are 1.976(5) and 1.989(5) Å. Similar values in the [Ag(CN)₂]^– anions are equal to 178.29(8)° and 2.081(3), 2.089 (3) Å, respectively. According to the X-ray analysis performed at 293 K on an automatic four-circle diffractometer D8 Quest Bruker (two-coordinate CCD detector, MoK_a radiation, l = 0.71073 Å, graphite monochromator), crystals 1 (C₂₂H₁₇N₃PAu, M 551.32, rhombic syngony P2₁2₁2₁, crystal size 0.42×0.20×0.15 mm), cell parameters: a = 8.430(5), b = 13.696(6), c = 18.000(7) Å;
α = 90.00 deg., β = 90.00 deg., γ = 90.00 deg.; V = 2078(4) Å³; the data collection area for 2q is 6.1–54.36 degrees, reflection index intervals –10 ≤ h ≤ 10, –17 ≤ k ≤ 17, –23 ≤ l ≤ 23; total reflections 32161; independent reflections 4597; R_int = 0.0296; GOOF 1.133; R₁ = 0.0241, wR₂ = 0.0548; residual electron density 0.36/–1.59 e/Å³; crystals 2 (C₂₇H₂₂N₂PAg, M 513.31, monoclinic syngony P2₁/s, crystal size 0.52×0.27×0.17 mm), cell parameters: a = 9.817(3), b = 15.131(6),
c = 15.347(5) Å; α = 90.00 deg., β = 90.638(12) deg., γ = 90.00 deg.; V = 2279.6(14) Å³; the data collection area for 2q is 6.7–72.86 degrees, the reflection index intervals are –16 ≤ h ≤ 16,
–25 ≤ k ≤ 25, –25 ≤ l ≤ 25; total reflections 67366; independent reflections 11062; R_int = 0.0316; GOOF 1.031; R₁ = 0.0403, wR₂ = 0.0925; residual electron density is 0.38/–0.74 e/Å³.

Author Biographies

M. A. Popkova, South Ural State University

кандидат биологических наук, доцент кафедры экологии ихимической технологии

V. V. Sharutin, South Ural State University

доктор химических наук, профессор, главный научныйсотрудник УНИД

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