A new method for synthesis of bismuth derivatives Ph4BiХ (X = Cl, NO3) and tetra-phenylbismuthonium mesitylenesulphonate

Authors

  • V. V. Sharutin South Ural State University
  • V. S. Senchurin South Ural State University
  • E. E. Shtol South Ural State University
  • V. V. Kroshnina South Ural State University

Keywords:

synthesis, ligand redistribution reaction, chloride, nitrate, tetraphenylbismuthonium mesity-lenesulfonate

Abstract

By reacting equimolar amounts of triphenylbismuth dichloride and dinitrate with penta-phenylbismuth in benzene, tetraphenylbismuthonium chloride and nitrate were synthesized, which in reaction with mesitylenesulfonic acid form tetraphenylbismuthonium mesitylenesulfonate with a yield of up to 73 %.

Author Biographies

V. V. Sharutin, South Ural State University

доктор химических наук, профессор, главный научный сотрудник управления научной и иннова-ционной деятельности

V. S. Senchurin, South Ural State University

доктор химических наук, доцент, профессор кафедры теоретической и прикладной химии

E. E. Shtol, South Ural State University

бакалавр кафедры теоретической и прикладной химии

V. V. Kroshnina, South Ural State University

бакалавр кафедры теоретической и прикладной химии

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Published

2024-09-06

Issue

Vol. 16 No. 2 (2024): Вестник Южно-Уральского государственного университета. Серия: Химия

Section

Inorganic chemistry