Interaction of 2,2'-bipyridyl with potassium dicyanoargentate

Authors

  • V. V. Sharutin South Ural State University
  • D. P. Shevchenko South Ural State University
  • N. V. Somov Nizhny Novgorod State University
  • М. V. Kudryashov Nizhny Novgorod State University

Keywords:

2, 2'-bipyridyl, potassium dicyanoargentate, alcohol, water, synthesis, complex, silver, structure, X-ray structural analysis

Abstract

The reaction of 2,2’-bipyridyl with potassium dicyanoargentate in aqueous alcohol solution yielded catena-[(2-cyano)-(2,2’-bipyridyl)-silver(I)], the structure of which was proven by X-ray diffraction analysis: (bpy)Ag(CN)2 (1) [C10.73H8AgN3.27, M = 290.61; monoclinic syngony, space group С2/с; cell parameters: a = 12.2677(2) Å, b = 8.60700(10) Å, c = 10.1225(2) Å; β = 106.871(2), V = 1022.81(3) Å3, Z = 4; calc = 1.887 g/cm3;  = 1.937 mm–1; F(000) = 569; collection area by q: 3.30430.500; total reflections 12678; independent reflections 1564 (Rint = 0.0249); GOOF = 1.094; R1-factor 0.0185]. Adduct 1 is a single-chain polymer with four-coordinated silver atoms linearly linked by disordered cyanide bridges.

Author Biographies

V. V. Sharutin, South Ural State University

доктор химических наук, главный научный сотрудник управления научной и инновационной деятельности

D. P. Shevchenko, South Ural State University

аспирант

N. V. Somov, Nizhny Novgorod State University

доктор физико-математических наук, профессор кафедры кристаллографии и экспериментальной физики

М. V. Kudryashov, Nizhny Novgorod State University

аспирант, инженер 2-й категории кафедры кристаллографии и экспериментальной физики

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Published

2025-12-13

Issue

Vol. 17 No. 4 (2025): Вестник Южно-Уральского государственного университета. Серия: Химия

Section

Inorganic chemistry