SOLID SOLUTION Cd<sub>x</sub>Pb<sub>1–x</sub>S FORECASTING BY SIMULATING OF SULPHIDES LEAD AND CADMIUM CO-PRECIPITATION PROCESS

Authors

  • Aleksey Yurevich Kirsanov Ural Federal University named after the first President of Russia B.N. Yeltsin. 28, Mira street, Ekaterinburg, 620002
  • Vyacheslav Filippovich Markov Ural Federal University named after the first President of Russia B.N. Yeltsin. 28, Mira street, Ekaterinburg, 620002
  • Larisa Nikolaevna Maskaeva Ural Federal University named after the first President of Russia B.N. Yeltsin. 28, Mira street, Ekaterinburg, 620002

Keywords:

cadmium sulfide, lead sulfide, hydrochemical precipitation, computer simulation, solid solution

Abstract

In the present paper the author has elaborated a model, which provides prognostication forecasting of solid solution CdxPb1-xS composition at co-precipitation of individual lead and cadmium sulphides. It has been shown that content of CdS in a solid solution has extreme characteristics depending on lead Pb2+ and cadmium Cd2+ ion concentration in a reactor. Satisfactory correlation  of simulation results with experimental data, obtained by X-ray analysis of the synthesized films, has been proved.

Author Biographies

Aleksey Yurevich Kirsanov, Ural Federal University named after the first President of Russia B.N. Yeltsin. 28, Mira street, Ekaterinburg, 620002

Postgraduate Student, Physical and Colloid Chemistry Subdepartment

Vyacheslav Filippovich Markov, Ural Federal University named after the first President of Russia B.N. Yeltsin. 28, Mira street, Ekaterinburg, 620002

Dr. Sc.  (Chemistry), Professor, Physical and Colloid Chemistry Subdepartment

Larisa Nikolaevna Maskaeva, Ural Federal University named after the first President of Russia B.N. Yeltsin. 28, Mira street, Ekaterinburg, 620002

Dr. Sc. (Chemistry), Professor, Physical and Colloid Chemistry Subdepartment

References

Марков, В.Ф. Гидрохимическое осаждение пленок сульфидов металлов / В.Ф. Марков, Л.Н. Маскаева, П.Н. Иванов. – Екатеринбург: УрО РАН, 2006. – 217 с.

Шелимова, Л.Е. Диаграммы состояния в полупроводниковом материаловедении (системы на основе халькогенидов Si, Ge, Sn, Pb) / Л.Е. Шелимова, В.Н. Томашик, В.И. Грыцив. – М.: Наука, 1991. – 368 с.

Марков, В.Ф. Механизм зародышеобразования пленок сульфидов металлов / В.Ф. Марков, Л.Н. Маскаева // Бутлеровские сообщения. – 2011. – Т. 24, № 2. – С. 33–41.

Марков, В.Ф. Особенности формирования пленок сульфидов металлов из водных растворов / В.Ф. Марков, Л.Н. Маскаева // Бутлеровские сообщения. – 2011. – Т. 24, № 2. – С. 42–50.

Второе начало термодинамики. Антология / С. Карно, Р. Клаузиус, В. Томсон и др. – М.: ЛКИ, 2007. – 312 с.

Дерягин, Б.В. Теория устойчивости коллоидов и тонких пленок / Б.В. Дерягин. – М.: Наука, 1986. – 206 с.

http://www.vasp.at

Published

2013-01-10

Issue

Section

Physical chemistry