SYNTHESIS AND STRUCTURE OF  BIS(4-BROMOPHENOXY)TRIPHENYLANTIMONY

Владимир Викторович Шарутин; Ольга Константиновна Шарутина

Authors

Владимир Викторович Шарутин Южно-Уральский государственный университет. 454080, г. Челябинск, пр. им. В.И. Ленина, 76
Ольга Константиновна Шарутина Южно-Уральский государственный университет. 454080, г. Челябинск, пр. им. В.И. Ленина, 76

Keywords:

bis(4-bromophenoxy)triphenylantimony, synthesis, molecular structure, X-ray analysis

Abstract

Interaction of triphenylantimony with 4-bromophenol in the presence of tert-butylhydroperoxide in ether has led to the synthesis of bis(4-bromophenoxy)triphenylantimony, whose structure has been established by X-ray diffraction analysis. The antimony atom has distorted trigonal-bipyramidal coordination with aroxy groups in axial positions. The bond lengths equal: 2.094(4), 2.108(5), 2.109(5) Å for Sb–C; 2.062(4) and 2.066(3) Å for Sb-O. The axial angle OSbO equals 172.41(1)°.

Author Biographies

Владимир Викторович Шарутин, Южно-Уральский государственный университет. 454080, г. Челябинск, пр. им. В.И. Ленина, 76

доктор химических наук, профессор, старший научный сотрудник УНИД

Ольга Константиновна Шарутина, Южно-Уральский государственный университет. 454080, г. Челябинск, пр. им. В.И. Ленина, 76

доктор химических наук, профессор, кафедра аналитической химии

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