SOME REACTIONS OF BIS(CYCLOPENTADIENYL)DIFERROCENYLTITAN

Григорий Алексеевич Разуваев; Владимир Викторович Шарутин

Authors

Григорий Алексеевич Разуваев Институт металлоорганической химии РАН
Владимир Викторович Шарутин Южно-Уральский государственный университет. 454080, г. Челябинск, пр. им. В.И. Ленина, 76.

Keywords:

bis(cyclopentadienyl)diferrocenyltitanium, reaction, iodine, carbonyl carbon

Abstract

Reaction of bis(cyclopentadienyl)diferrocenyltitanium Cp2TiFc2 (1) with iodine (toluene, 20C, 24 h) proceeds with formation of bis(cyclopentadienyl)titanium diiodide Cp2TiI2 (2) and diferrocenyl Fc-Fc (3); a byproduct of the reaction is the salt Fc-FcI3 (4). Interaction of 1 with carbon monoxide (100 bar, benzene, 50 °C, 3 h) leads to the synthesis of diferrocenylketone (5) and bis(cyclopentadienyl) titanium dicarbonyl (6).

Author Biography

Владимир Викторович Шарутин, Южно-Уральский государственный университет. 454080, г. Челябинск, пр. им. В.И. Ленина, 76.

доктор химических наук, профессор, старший научный сотрудник УНИД

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