Peculiarities of the reactions of tri(meta-tolyl)antimony and tri(ortho-tolyl)antimony with 2-nitrobenzaldoxime. The molecular structures of bis(2-nitrobenzaldoximato)tri(meta-tolyl)antimony, µ2-oxo-bis[(2-nitrobenzaldoximato)tri(meta-tolyl)antimony] and bis(2-nitrobenzaldoximato)tri(ortho-tolyl)antimony

V V Sharutin; O K Sharutina; E V Artemeva; M S Makerova

Authors

V V Sharutin South Ural State University, Chelyabinsk, Russian Federation
O K Sharutina South Ural State University, Chelyabinsk, Russian Federation
E V Artemeva South Ural State University, Chelyabinsk, Russian Federation
M S Makerova South Ural State University, Chelyabinsk, Russian Federation

Keywords:

tri(m-tolyl)antimony, tri(o-tolyl)antimony, 2-nitrobenzaldoxime, tert-butyl hydroperoxide, hydrogen peroxide, oxidizing reactions, bis(2-nitrobenzaldoximato)- tri(m-tolyl)antimony, µ2-oxo-bis[(2-nitrobenzaldoximato)tri(m-tolyl)antimony],

Abstract

Bis(2-nitrobenzaldoximato)tri(meta-tolyl)antimony (1), µ₂-oxo-bis[(2-nitrobenzaldoximato)-tri(meta-tolyl)antimony] (2) and bis(2-nitrobenzaldoximato)tri(ortho-tolyl)antimony (3) have been obtained by the reactions of tri(meta-tolyl)antimony and tri(ortho-tolyl)antimony with 2-nitrobenzaldoxime in the presence of an oxidizing agent (hydrogen peroxide or tert-butyl hydroperoxide). Compounds 1–3 have been characterized by X-ray diffraction analysis.

Author Biographies

V V Sharutin, South Ural State University, Chelyabinsk, Russian Federation

доктор химических наук, профессор, старший научный сотрудник УНИД

O K Sharutina, South Ural State University, Chelyabinsk, Russian Federation

доктор химических наук, профессор, кафедра аналитической химии

E V Artemeva, South Ural State University, Chelyabinsk, Russian Federation

студент химического факультета

M S Makerova, South Ural State University, Chelyabinsk, Russian Federation

студент химического факультета

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