Features of L-Amino Acid Adsorption on Nanocrystalline Anatase

Authors

  • Oleg I Bol’shakov South Ural State University, Chelyabinsk
  • Vladimir V Potemkin South Ural State University, Chelyabinsk
  • Mariya A Grishina South Ural State University, Chelyabinsk
  • Alexey S Galushko Institute of Organic Chemistry of the Russian Academy of Sciences, Moscow, Russian Federation
  • Sergey V Merzlov South Ural State University, Chelyabinsk, Russian Federation
  • Roman S Morozov South Ural State University, Chelyabinsk
  • Artyom O Shchelokov South Ural State University, Chelyabinsk
  • Vadim V Popov Wayne State University, Detroit, MI, USA

DOI:

https://doi.org/10.14529/chem170101

Keywords:

titanium oxide, anatase, nanoparticles, L-amino acid, adsorption, IR-spectroscopy, NMR-spectrometry

Abstract

Affinity characteristics of biomolecules, such as peptides and proteins, towards inorganic surfaces in general and to titanium oxide in particular become crucial in biotechnology and bionanotechnology. Amino acids are often used as “model” bits of peptides or proteins for studying their properties in different environments, and/or developing functional surfaces. Despite the great demand for knowledge about amino acid interactions with metal oxide surface, studies on the issue lack in consistency and represent a fragmentary picture. This paper is an attempt to study amino acid adsorption on nanocrystalline anatase systematically at uniform conditions. Features of the L-alanine adsorption have been revealed and interpreted with quantum-chemical calculations.

Author Biographies

Oleg I Bol’shakov, South Ural State University, Chelyabinsk

кандидат химических наук, научный сотрудник Управления научной и инновационной деятельности

Vladimir V Potemkin, South Ural State University, Chelyabinsk

научный сотрудник Управления научной и инновационной деятельности

Mariya A Grishina, South Ural State University, Chelyabinsk

главный научный сотрудник Высшей медико-биологической школы

Alexey S Galushko, Institute of Organic Chemistry of the Russian Academy of Sciences, Moscow, Russian Federation

аспирант лаборатории металлокомплексных и наноразмерных катализаторов (№ 30)

Sergey V Merzlov, South Ural State University, Chelyabinsk, Russian Federation

инженер кафедры экологии и природопользования, химический факультет

Roman S Morozov, South Ural State University, Chelyabinsk

аспирант кафедры экологии и природопользования

Artyom O Shchelokov, South Ural State University, Chelyabinsk

студент кафедры химической технологии

Vadim V Popov, Wayne State University, Detroit, MI, USA

постдокторант факультета биомедицинской инженерии, Университет Уэйна

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Published

2017-03-07

Issue

Vol. 9 No. 1 (2017)

Section

Inorganic chemistry