Натриевые химические источники тока с катодами на основе сульфидов меди

D. C. Linnik; T. B. Polishchuk; V. A. Glazunova; D. A. Zherebtsov; D. A. Vinnik; T. N. Mogila; D. V. Aleshkina

Authors

D. C. Linnik Donetsk National University
T. B. Polishchuk Donetsk National University
V. A. Glazunova Donetsk Institute for Physics and Engineering named after A.A. Galkin
D. A. Zherebtsov South Ural State University
D. A. Vinnik South Ural State University
T. N. Mogila Donetsk National University
D. V. Aleshkina South Ural State University

Keywords:

chemical current source, sodium anode, nanosized copper sulfide

Abstract

In the work, cells consisting of sodium and copper sulfides with different composition, structure, and morphology of the cathode material were investigated as chemical current sources. A decrease in the characteristic particle size of CuS from 0.4–5 μm to 10–50 nm led to an increase in the initial operating voltage from 1.87 V to 2.55 V and capacity from 166 mAh·g^–1 to 400 mAh·g^–1. The superstoichiometric incorporation of sulfur into nanosized copper sulfide CuS_1+x leads to a decrease in the initial operating voltage of the cell by 0.23 V, while the capacity increases from 400 mAh·g^–1 to 431 mAh·g^–1. In the case of sulfide of the Cu₂S composition, the capacity of the cell with the sodium anode is 121 mAh·g^–1, in addition, this material, like microcrystalline copper sulfide of the CuS composition, is prone to surface passivation with sulfides of variable composition. A comparative analysis of the electrochemical parameters of sodium and lithium current sources with cathode materials based on copper sulfides of different composition and morphology is carried out

Author Biographies

D. C. Linnik, Donetsk National University

младший научный сотрудник, ассистент кафедры физической химии

T. B. Polishchuk, Donetsk National University

научный сотрудник, ассистент кафедры физической химии

V. A. Glazunova, Donetsk Institute for Physics and Engineering named after A.A. Galkin

научный сотрудник, отдел физики высоких давлений и перспективных технологий

D. A. Zherebtsov, South Ural State University

кандидат химических наук, старший научный сотрудник, кафедра материаловедения и физико-химии материалов, инженер НОЦ «Нанотехнологии»

D. A. Vinnik, South Ural State University

доктор химических наук, доцент, доцент кафедры материаловедения и физико-химии материалов

T. N. Mogila, Donetsk National University

инженер II категории, аспирант кафедры физической химии

D. V. Aleshkina, South Ural State University

магистрант

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