Строение минорных продуктов реакций дииододицианоаурата калия с галогенидами тетраорганилфосфора и –сурьмы

V. V. Sharutin

Authors

V. V. Sharutin South Ural State University, Chelyabinsk, Russian Federation

Keywords:

structure, complex, triphenylorganylphosphonium, diiododicyanoaurate, tetraarylstibonium, iodine, X-ray diffraction analysis

Abstract

The structure of four complexes, minor products of potassium diiododicyanoaurate reactions with tetraorganylphosphonium and -stibonium halides [Ph₃PEt]₂[Au(CN)₂I₂][I₃] (1), [Ph₃PCH₂СN]₂[Au(CN)₂I₂][I₃] (2), [p-Tol₄Sb]₂[Au(CN)₂I₂][I₃] (3), and [Ph₄Sb]₂[Au(CN)₂I₂][I₃]×2I₂ (4) in acetonitrile or water, was determined by X-ray structural analysis, performed on an automatic four-circle diffractometer D8 Quest Bruker (МоК_α, λ = 0.71073 Å, 293 К. 1 (C₄₂H₄₀AuI₅N₂P₂, P-1, a = 7.865(4), b = 9.933(4), c = 16.437(6) Å, a = 97.204(14), β = 98.789(19), g = 110.82(2) deg., V = 1163.5(8) Å³, Z = 1, R₁ = 0,0467, wR₂ = 0,1173. 2 (C₄₂H₃₄AuI₅N₄P₂, P-1, a = 8.490(4),
b = 11.563(4), c = 13.625(6) Å, a = 66.287(19), β = 74.57(2), g = 76.283(19) deg.,
V = 1167.6(9) Å³, Z = 1, R₁ = 0.0848, wR₂ = 0.2079. 3 (C₅₈H₅₆AuI₅N₂Sb₂, P-1, a = 9.984(4),
b = 10.073(4), c = 15.749(9) Å, a = 93.581(18), β = 101.91(2), g = 95.342(15) deg.,
V = 1537.5(12) Å³, Z = 1, R₁ = 0.0612, wR₂ = 0.1704. 4 (C₅₀H₄₁AuI₈N₂Sb₂, P-1, a = 10.057(8),
b = 14.131(10), c = 21.243(12) Å, a = 81.28(2), β = 85.68(3), g = 81.17(4) deg., V = 2944(3) Å³, Z = 2, R₁ = 0.0488, wR₂ = 0.1080.

Author Biography

V. V. Sharutin, South Ural State University, Chelyabinsk, Russian Federation

доктор химических наук, главный научный сотрудник управления научной и инновационной деятельностиСтроение минорных продуктов реакций дииододицианоаурата калия с галогенидами тетраорганилфосфора и –сурьмы

References

Bruker. SMART and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System. Bruker AXS Inc., Madison, Wisconsin, USA, 1998.

Bruker. SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Display-ing Crystal Structures From Diffraction Data. Bruker AXS Inc., Madison, Wisconsin, USA, 1998.

OLEX2: a Complete Structure Solution, Refinement and Analysis Program / O.V. Dolomanov, L.J. Bourhis, R.J. Gildea et al. // J. Appl. Cryst. – 2009. – V. 42. – P. 339–341. DOI: 10.1107/S0021889808042726.

Синтез и кристаллические структуры гексахлороплатината, тетрахлороаурата и гексахло-ростанната тетрафенилсурьмы(V) [Ph4Sb]+2[PtCl6]2–, [Ph4Sb]+[AuCl4]–, [Ph4Sb]+2 [SnCl6]2– / В.В. Шарутин, В.С. Сенчурин, О.А. Фастовец и др. // Коорд. химия. – 2008. – Т. 34, № 5. – С. 373–379.

Синтез и строение комплексов золота и меди: [Ph3PCH2Ph]+[AuCl4]–, [NH(C2H4OH)3]+[AuCl4]– ∙ H2O и [Ph3EtP]+2[Cu2Cl6]2– / В.В. Шарутин, В.С. Сенчурин, О.К. Шару-тина и др. // Журн. неорган. химии. – 2010. – Т. 55, № 9. – С. 1499–1505.

Шарутин, В.В. Синтез и строение комплексов золота [Ph3PCH2CH=CHCH2PPh3]2+[AuCl4]–2 и [Ph3PCH2CH2COOH]+[AuCl4]– / В.В. Шарутин, О.К. Шарутина, В.С. Сенчурин // Журн. неорган. химии. – 2015. – Т. 60, № 8. – С. 1040–1044. DOI: 10.7868/S0044457X15080188.

Шарутин, В.В. Синтез и строение комплексов золота [Ph3P(CH2C6H4F-4)]+[AuCl4]– и [Ph3PCH2CH=CHMe]+[AuCl4]– / В.В. Шарутин, О.К. Шарутина, В.С. Сенчурин // Журн. общ. хи-мии. – 2016. – Т. 86, № 10. – С. 1709–1713.

Leznoff, D.B. Coordination Polymers with Cyanoaurate Building Blocks: Potential New Industrial Applications for Gold / D.B. Leznoff, J. Lefebvre // Gold Bulletin. – 2005. – V. 38, Iss. 2. – P. 47–54. DOI: 10.1007/BF03215233.

Shaw, III, C.F. Gold-based Therapeutic Agents / C.F. Shaw III // Chem. Rev. – 1999. – V. 99. –P. 2589−2600. DOI: /10.1021/cr980431o.

Rawashdeh-Omary, M.A. Oligomerization of Au(CN)2- and Ag(CN)2-ions in Solution Via Ground-state Aurophilic and Argentophilic Bonding / M.A. Rawashdeh-Omary, M.A. Omary, H.H. Patterson // J. Am. Chem. Soc. – 2000. – V. 122. – P. 10371–10380. DOI: 10.1021/ja001545w.

Assefa, Z. Hydrothermal Syntheses, Structural, Raman, and Luminescence Studies of Cm[M(CN)2]3 3H2O and Pr[M(CN)2]33H2O (M = Ag, Au): 2. Hetero-bimetallic Coordination Polymers Consisting of Trans-plutonium and Transition Metal Elements / Z. Assefa, R.G. Haire, R.E. Sykora // J. Solid State Chem. – 2008. – V. 181. – P. 382–391. DOI: 10.1016/j.jssc.2007.11.036.

Tunable Photoluminescence of Closed-shell Heterobimetallic Au–Ag Dicyanide Layered Systems / J.C.F. Colis, Ch.Larochelle, E.J. Ferna´ndez et. al. // J. Phys. Chem. B. – 2005. – V. 109. – P. 4317–4323. DOI: 10.1021/jp045868g.

Hydrothermal Synthesis, Structural, Raman, and Luminescence Studies of Am[M(CN)2]3x3H2O and Nd[M(CN)2]3x3H2O (M=Ag, Au): Bimetallic Coordination Polymers Containing Both Trans-plutonium and Transition Metal Elements / Z. Assefa, K. Kalachnikova, R.G. Hairec et al. // J. Solid State Chem. – 2007. – V. 180. – P. 3121–3129. DOI: 10.1016/j.jssc.2007.08.032.

Roberts, R.J. Color-tunable and White-light Luminescence in Lanthanide−Dicyanoaurate Coordination Polymers / R.J. Roberts, D. Le, D.B. Leznoff // Inorg. Chem. – 2017. – V. 56, iss. 14. – P. 7948–7959. DOI: 10.1021/acs.inorgchem.7b00735.

Шарутин, В.В. Синтез и строение дицианоауратов органилтрифенилфосфония [Ph3PR]+[Au(CN)2]–, R = CH2С(O)Ph, CHCНMe, (CH2)4Br / В.В. Шарутин, О.К. Шарутина, М.А. Попкова // Журн. неорган. химии. – 2019. – Т. 64. – № 6. – С. 607–612. DOI: 10.1134/S0044457X1906014X

Ovens, J.S. Thermally Triggered Reductive Elimination of Bromine from Au(III) as a Path to Au(I)-based Coordination Polymers / J.S. Ovens, D.B. Leznoff // Dalton Trans. – 2011. – V. 40. – P. 4140–4146. DOI: 10.1039/C0DT01772H.

The Use of Polarizable [AuX2(CN)2]− (X = Br, I) Building Blocks Toward the Formation of Birefringent Coordination Polymers / J.S. Ovens, A.R. Geisheimer, A.A. Bokov et al. // Inorg. Chem. – 2010. – V. 49, iss. 20. – P. 9609–9616. DOI: 10.1021/ic101357y.

Crystal Structures and Properties of [Au(phen){(CN)0.92Br0.08}2]Br and [Au(phen)(CN){(CN)0,82Br0,18}]•0.5trans-[Au(CN)2Br2]•0,5Br•phen (phen = 1,10-phenanthroline) Ob-tained by Disproportionation of Five-co-ordinate Bromodicyano(1,10-phenanthroline)gold(III). Two Examples of Secondary Coordination and CN/Br Disorder in Square-planar Gold(III) Complexes / G. Marangoni, B. Pitteri, V. Bertolasi et al. // J. Chem. Soc., Dalton Trans. – 1987. – P. 2235–2240. DOI: 10.1039/DT9870002235.

Ovens, J.S. Raman Detected Sensing of Volatile Organic Compounds by Vapochromic Cu[AuX2(CN)2]2 (X = Cl, Br) Coordination Polymer Materials / J.S. Ovens, D.B. Leznoff // Chem. Mater. – 2015. – V. 27, № 5. – P. 1465–1478. DOI: 10.1021/cm502998w.

Ovens, J.S. Targeting [AuCl2(CN)2]− Units as Halophilic Building Blocks in Coordination Polymers / J.S. Ovens, K.N. Truong, D.B. Leznoff // Inorg. Chim. Acta. – 2013. – V. 403. – P. 127–135. DOI: 10.1016/j.ica.2013.02.011.

Ovens, J.S. Structural Organization and Dimensionality at the Hands of Weak Intermolecular Au⋯Au, Au⋯X and X⋯X (X = Cl, Br, I) Interactions / J.S. Ovens, K.N. Truong, D.B. Leznoff // Dal-ton Trans. – 2012. – V. 41. – P. 1345–1351. DOI: 10.1039/C1DT11741F.

BEDT-TTF Salts with Square-Planar Gold(III) Complex Anions: β-(ET)2AuCl4 and (ET)2Au(CN)2Cl2. / U. Geiser, B.A. Anderson, A. Murray et al. // Mol. Cryst. Liq. Cryst. – 1990. – V. 181, iss. 1. – P. 105–116. DOI: 10.1080/00268949008035996.

Pitteri, B. Chelate Polypyridine Ligand Rearrangement in Au(III) / B. Pitteri, M. Bortoluzzi, V. Bertolasi // Complexes Transition Met. Chem. – 2008. – V. 33, № 5. – P. 649–654. DOI: 10.1007/s11243-008-9092-9.

Шарутин, В.В. Синтез и строение комплексов циркония [PhPR]+[ZrCl]2–, R = Et, CH2PH, CH2C(O)OMe / В.В. Шарутин, О.К. Шарутина, Е.В. Лобанова // Журн. неорган. химии. – 2018. – Т. 63, № 12. – С. 1549–1554. DOI: 10.1134/S0044457X1812019X.

Синтез и строение комплексов циркония [Et2H2N]+2[ZrCl6]2–, [Me3NCH2Ph]+2[ZrCl6]2–•

•MeCN, [Ph3PC6H4(CHPh2-4)]+2[ZrCl6]2–•2 MeCN И [Ph4Sb]+2[ZrCl6]2– / В.В. Шарутин, О.К. Шарутина, Н.М. Тарасова и др. // Известия Академии наук. Серия химическая. – 2019. – № 1. – С. 24–31.

Parvez, M. Tetraphenylphosphonium Triiodide / M. Parvez, M. Wang, P.M. Boorman // ActaCrystallogr., Sect. C: Cryst. Struct. Commun. – 1996. – V. 52. – P. 377–378. DOI: 10.1107/S0108270195010456.

Binary Polyazides of Cerium and Gadolinium / K. Rosenstengel, Axel Schulz, O. Niehaus et al. // Eur. J. Inorg. Chem. – 2018. – Iss.6. – P. 778–790. DOI: 10.1002/ejic.201701408.

Solid-state Structures of Triarylantimony Dihalides; the Isolation of Some Mixed-halide Spe-cies and Crystal Structures of Ph3SbI2 and [Ph4Sb]I3. / N. Bricklebank, S.M. Godfrey, H.P. Lane et al. //J.Chem.Soc.,Dalton Trans. – 1994. – Iss. 12. – P. 1759–1763. DOI: 10.1039/DT9940001759.

Синтез и строение сольвата трииодида [(μ4-сукцинато)гексадекафенилтетрасурьмы] сбензолом [(Ph4Sb)2O2CCH2CH2CO2(Ph4Sb)2][I3]2 •4PhH / В.В. Шарутин, О.К. Шарутина, Ю.О. Губанова и др. // Координационная химия. – 2017. – Т. 43, № 7. – С. 444–448. DOI: 10.7868/S0132344X17060093.

Бацанов, С.С. Атомные радиусы элементов / С.С. Бацанов // Журн. неорган. химии. – 1991. – Т. 36, № 12. – С. 3015–3037.