Toxicity of exhaust gases in gasoline engines powered with com-pressed natural gas and gasoline

Authors

  • N. M. Smolenskaya Togliatti State University, Togliatti
  • V. V. Smolenskii Togliatti State University, Togliatti

Keywords:

compressed natural gas, gasoline, hydrogen, exhaust gas toxicity, spark-ignition engine

Abstract

The need to reduce environmental stress caused by active use of vehicles in large cities calls for reducing the toxicity of exhaust gases emitted by gasoline engines with spark ignition. The research aimed to find ways to reduce the toxicity of exhaust gases emitted by spark-ignition engines.
The studies were carried out on a single-cylinder UIT-85 simulating the working process under maximum load and on a VAZ-2111 engine in idle mode. These modes have the greatest impact on the toxicity of a gasoline engine. Experimental studies on the VAZ-2111 engine were conducted at a standard compression ratio of 9.8 and at a reduced compression ratio of 7.5 using a special four-millimeter-thick aluminum plate. During the experimental studies, we recorded the pressure in
the engine cylinder, the electrical conductivity of the flame in the zones of ionization sensors,
as well as the consumption of fuel and air at the inlet and the toxicity characteristics of the exhaust gases. Gasoline and compressed natural gas were used as fuel. To assess the potential for reducing toxicity by intensifying the combustion process in VAZ-2111 engine, we used a hydrogen additive in the amount of 4 % (0.02 kg / h) and 6 % (0.03 kg / h) of the fuel mass. When studying UIT-85, we used a 5 % hydrogen additive for gasoline and a 5, 10, 15 % hydrogen additive for compressed natural gas. It was shown that natural gas can reduce the toxicity of exhaust gases, reducing the content of nitrogen oxides, hydrocarbons, and carbon monoxide. The engine performance indicators remain the same, if the optimal ignition dwell angles are selected. For efficient combustion at idle mode, methods for intensifying the combustion process have to be applied. We showed an example of effective impact of hydrogen additive in amount of 4 % of the fuel mass. At the same time, the effect of hydrogen is more effective when engines are powered with natural gas.

Author Biographies

N. M. Smolenskaya, Togliatti State University, Togliatti

кандидат технических наук, доцент кафедры «Общая и теоретическая физика»

V. V. Smolenskii, Togliatti State University, Togliatti

кандидат технических наук, доцент, доцент кафедры «Энергетические машины и системы управления»

References

Wallington T. J., Kaiser E. W., Farrell J. T. Automotive Fuels and Internal Combustion Engines: A Chemical Perspective. The Royal Society of Chemistry, 2006, vol. 35, pp. 335–347. DOI: 10.1039/B410469M

Das L., Gulati R., Gupta P. Comparative Evaluation of the Performance Characteristics of a Spark Ignition Engine Using Hydrogen and Compressed Natural Gas as Alternative Fuels. International Journal of Hydrogen Energy, 2000, vol. 25 (8), pp. 783–93. DOI: 10.1016/S0360-3199(99)00103-2

Ranjan R., Tyagi R.K. Emission Characteristic of Hydrogen and Gasoline Blend in Spark-Ignited Engine. International Journal of Ambient Energy, 2015. DOI: 10.1080/01430750.2015.1023840

Das L.M. Hydrogen Engine: Research and Development Programmes in Indian Institute of Technology, Delhi. International Journal of Hydrogen Energy, 2002, vol. 27 (9), pp. 953–65. DOI: 10.1016/S0360-3199(01)00178-1

Unich A., Morrone B., Mariani A. The Impact of Natural Gas – Hydrogen Blends on Internal Combustion Engines Performances and Emissions. SAE Paper, 2009, 2009-24-0102. DOI: 10.4271/2009-24-0102

Sierens R., Rosseel E. Variable Composition Hydrogen/Natural Gas Mixtures for Increased Engine Efficiency and Decreased Emissions. Eng. Gas Turbines Power, vol. 122, iss. 1, pp. 135–140. DOI: 10.1115/1.483191

Mohammed S.E., Baharom M.B., Aziz A.R. Analysis of Engine Characteristics and Emissions Fueled by In-Situ Mixing of Small Amount of Hydrogen in CNG. International Journal of Hydrogen Energy, 2011, vol. 36 (6), pp. 4029–4037. DOI: 10.1016/j.ijhydene.2010.12.065

Ma F. Wang Y., Liu H.Q., Li Y. Experimental Study on Thermal Efficiency and Emission Characteristics of a Lean Burn Hydrogen Enriched Natural Gas. International Journal of Hydrogen Energy, 2007, vol. 32, pp. 5067–5075. DOI: 10.1016/j.ijhydene.2007.07.048

Wallace J.S., Cattelan A.I. Hythane and CNG Fuelled Engine Exhaust Emission Comparison. Proceedings 10th World Hydrogen Energy Conference, 1994, pp.1761–1770.

Al-Janabi H., Al-Baghdadi S. A Prediction Study of the Effect of Hydrogen Blending on the Performance and Pollutants Emission of a Four Stroke Spark Ignition Engine. International Journal of Hydrogen Energy, 1999, vol. 24, pp. 363–375.

Chatterjee A., Dutta S., Mandal B.K. Combustion Performance and Emission Characteristics of Hydrogen as an Internal Combustion Engine Fuel. Journal of Aeronautical and Automotive Engineering (JAAE), 2014, vol. 1, no. 1, September, pp. 1–6.

Tinaut F.V., Melgar A., Gimenez B., Reyes M. Prediction of Performance and Emissions of an Engine Fuelled with Natural Gas/Hydrogen Blends. International Journal of Hydrogen Energy, 2011, vol. 36, pp. 947–956. Available at: https://doi.org/10.1016/j.ijhydene.2010.10.025.

Andrea T.D., Henshaw P.F., Ting D.S.K. Formation and Restraint of Toxic Emissions in Hydrogen-Gasoline Mixture Fuelled Engine. International Journal of Hydrogen Energy, 1998, vol. 23, pp. 971–975. DOI: 10.1016/S0360-3199(97)00141-9

Ji C., Wang S. Effect of Hydrogen Addition on Combustion and Emissions Performance of a Spark Ignition Gasoline Engine at Lean Conditions. International Journal of Hydrogen Energy, 2009, vol. 34, pp. 7823–7834. DOI: 10.1016/j.ijhydene.2009.06.082

Zervas E., Montagne X., Lahaye J. Influence of Fuel and Air/Fuel Equivalence Ratio on the Emission of Hydrocarbons from a SI Engine. Fuel, 2004, vol. 83 (17–18), pp. 2301–2311. DOI: 10.1016/j.fuel.2004.06.029

Smolenskaya N.M., Smolenskii V.V., Bobrovskij I. Research of Polytropic Exponent Changing for Influence Evaluation of Actual Mixture Composition on Hydrocarbons Concentration Decreasing on Deep Throttling Operation. IOP Conf. Series: Earth and Environmental Science, 2017, vol. 50, 012016. DOI: 10.1088/1755-1315/50/1/012016

Smolenskaya N.M., Smolenskii V.V., Korneev N.V. Increase in the Thermodynamic Effi-ciency of the Working Process of Spark-Ignited Engines on Natural Gas with the Addition of Hyd-rogen. IOP Conf. Series: Earth and Environmental Science, 2018, vol. 121, 052009. DOI: 10.1088/1755-1315/121/5/052009

Li H., Karim G.A. Knock in Spark Ignition Hydrogen Engine. International Journal of Hydrogen Energy, 2004, vol. 29 (8), pp. 859–65. Available at: https://doi.org/10.1016/j.ijhydene.2003.09.013.

Sharma S.K., Goyal P. and Tyagi R.K. Hydrogen-Fueled Internal Combustion Engine: A Review of Technical Feasibility. International Journal of Performability Engineering, 2015, vol. 11, no. 5, September, pp. 491–501.

Xu J., Zhang X., Liu J., Fan L. Experimental Study of a Single Cylinder Engine Fueled with Natural Gas – Hydrogen Mixtures. International Journal of Hydrogen Energy, 2010, vol. 35 (7), pp. 2909–2914. DOI: 10.1016/j.ijhydene.2009.05.039

Kahraman E., Ozcanlı S.C., Ozerdem B. An Experimental Study on Performance and Emission Characteristics of a Hydrogen Fuelled Spark Ignition Engine. International Journal of Hydrogen Energy, 2007, vol. 32, pp. 2066–2072. DOI: 10.1016/j.ijhydene.2012.09.037

Published

2019-01-11

Issue

Section

Verification and test