СТРОЕНИЕ ДИБЕНЗОИЛМЕТАНАТА ТЕТРАФЕНИЛСУРЬМЫ. ФАКТОРЫ, ВЛИЯЮЩИЕ НА ПРОЧНОСТЬ СВЯЗЫВАНИЯ ЛИГАНДА В β-ДИКЕТОНАТНЫХ КОМПЛЕКСАХ СУРЬМЫ (V)

Владимир Викторович Шарутин, Ольга Константиновна Шарутина

Аннотация


Дибензоилметанат тетрафенилсурьмы (1) синтезирован по реакции замещения из пентафенилсурьмы и дибензоилметана (2) в толуоле. В  молекуле 1 лиганд бидентатен, координация атома сурьмы октаэдрическая (транс-углы CSbO и CSbC 165,7(1)°, 168,7(1)° и 159,4(2)°, расстояния Sb–O 2,256(3), 2,235(3) Å, Sb–С 2,157(4)–2,170(4) Å). В кристалле соединение 2 находится в енольной форме, длины связей C=O и C–O равны 1,283(2) и 1,303(2) Å.


Ключевые слова


дибензоилметанат тетрафенилсурьмы; дибензоилметан; молекулярные структуры; рентгеноструктурный анализ

Полный текст:

PDF (English)

Литература


Meinema H.A., Noltes I.G. Preparation and Properties of Ogano(acetylacetonato)antimony(V) Compounds. J. Organomet. Chem., 1969, vol. 16, no. 2, pp. 257–263.

Matsumura Y., Okawara R. Hexacoordinated Tetraphenylantimony Complexes. Inorg. Nucl. Chem. Lett., 1968, vol. 4, no. 9, pp. 521–524.

Singhal K., Aggarwal A.K., Ray P. Studieson β-Diketonate and β-Diketones ter Derivatives of Tri- and Tetraorganoantimony(V). Indian J. Chem., 1992, vol. 31A, no. 10, pp. 797–799.

Jain V.K., Bohra B., Mehrotra R.C. Synthesis and Spectral Studies of (1,3-Diketonato)-Triphenylantimony(V) Complexes. J. Organomet. Chem., 1980, vol. 184, no. 1, pp. 57–62.

Otero A., Royo P. Pentafluorophenylantimony Compounds. J. Organomet. Chem., 1978, vol. 154, no. 1, pp. 13–19.

Espinosa A., Barbero A.J., Sanchez J.M.G., Sanchez G.G. Pentahalophenyl Derivatives of Antimony(V) with Bidentate Ligands. An. Quim., 1983, vol. 79B, no. 2, pp. 217–220.

Sarutin V.V., Sharutina O.K., Zadachina O.P., Senchurin V.S., Guhman E.V., Reutov V.A., Shapkin N.P. Synthesis of Tetraarylantimony β-Diketonates from Pentaarylantimony and β-Diketones. [Cintez β-diketonatov tetraarilsur'my iz pentaarilsur'my i β-diketonov]. Zhurn. Obshch. Himii [Russian Journal of General Chemistry], 2000, vol. 70, no. 5, pp. 746–747.

Kanehisa N., Onuma K., Uda S., Hirabayashi K., Kai Y., Yasuoka N. The Crystal and Molecular Structures of three Acetylacetonato-Organoantimony(V) Compounds [(acac)RnSbX4-n]. Bull. Chem. Soc. Japan, 1978, vol. 51, no. 8, pp. 2222–2233.

Kroon J., Hulscher J.B., Peerdeman A.F. The Molecular Structure of (Acetylacetnato)-Dichlorodiphenylantimony in the Crystalline State. J. Organomet. Chem., 1972, vol. 37, no. 2, pp. 297–301.

Sharutin V.V., Sharutina O.K. Crystal and Molecular Structure of Tetraphenylantimony Acetylacetonate. [Kristallicheskaya i molekulyarnaya struktura acetilacetonata tetrafenilsur'my]. Butlerovskie soobshcheniya [Russian Journal Butlerov Communication], 2014, vol. 38, no. 5, pp. 118–121.

Sarutin V.V., Sharutina O.K., Zadachina O.P., Zaharova A.N., Reutov V.A., Shapkin N.P., Bel'skij V.K. Synthesis and Structure of Chloroacetylacetonate Tetraphenylantimony. [Sintez i stroenie hloracetilacetonata tetrafenilsur'my]. Zhurn. Obshch. Himii [Russian Journal of General Chemistry], 2000, vol. 70, no. 10, pp. 1672–1674.

Sharutin V.V., Sharutina O.K., Zadachina O.P., Litvinova S.A., Reutov V.A., Gerasimenko A.V., Gerasimenko E.A., Bukveckij B.I., Popov D.Yu. Synthesis and Structure of Tetraphenylantmony γ-Alkylacetylacetonate. [Sintez i stroenie γ-alkilacetilacetonatov tetrafenilsur'my]. Koord. Himiya [Russian Journal of Coordination Chemistry], 2003, vol. 29, no. 1, pp. 8–12.

Sharutin V.V., Pakusina A.P., Sharutina O.K., Zadachina O.P., Fedorenko E.V. Gerasimenko A.V., Pushilin M.A. Synthesis and Structure of Tetraphenylantimony γ-Phenylacetylacetonate. [Sintez i stroenie γ-fenilacetilacetonata tetrafenilsur'my]. Himiya i komp'yuternoe modelirovanie. Butlerovskie soobshcheniya [Russian Journal Butlerov Communication], 2003, vol. 4, no. 1, pp. 34–35.

Sharutin V.V., Pakusina A.P., Egorova I.V., Sharutina O.K., Fukin G.K. Synthesis and Structure of γ-Phenyl- and γ-Thiobutylacetylacetonate Tetraphenylantimony [Sintez i stroenie γ-fenil- i γ-tiobutilacetilacetonatov tetrafenilsur'my]. Koord. Himiya [Russian Journal of Coordination Chemistry], 2008, vol. 34, no. 4, pp. 267–271.

Sharutina O.K., Sharutin V.V. Molekuljarnye struktury organicheskih soedinenij sur'my (V). [The Molecular Structure of Organic Compounds Antimony (V)]. Chelyabinsk, South Ural St. Univ. Publ., 2012, 395 p.

Bruker (2000) SMART. Bruker Molecular Analysis Research Tool, Versions 5.625 Bruker AXS, Madison, Wisconsin, USA.

Bruker (2000) SAINTPlus Data Reduction and Correction Program Versions 6.02a, Bruker AXS, Madison, Wisconsin, USA.

Gerard G., Lucken E.A.C., Bernardinelli G. Nuclear Quadrupole Resonance Studies of Chelated Antimony Complex. J. Chem. Soc. Perkin II, 1986, pp. 879–882.

Korte L., Mootz D., Scherf M., Wiebcke M. Structures of two Acetylacetonate Complex: Sb(Acac)Cl4 and (NHEt3)[Sn(Acac)Cl4]. Acta Crystallogr., 1988, vol. C44, pp. 1128–1130.

Bacanov S.S. Atomic Radii of the Elements [Atomnye radiusy jelementov]. Zhurn. Neorgan. Himii [Russian Journal of Inorganic Chemistry], 1991, vol. 36, no. 12, pp. 3015–3037.


Ссылки

  • На текущий момент ссылки отсутствуют.