SYNTHESIS AND STRUCTURE OF IODOTRIS(TRYPHENYLSTIBINE)SILVER [(Ph3Sb)3AgI]

Владимир Викторович Шарутин, Ольга Константиновна Шарутина, Владислав Станиславович Сенчурин, Анастасия Николаевна Неудачина, Павел Валерьевич Андреев

Аннотация


Interaction of silver iodide with triphenylstibine in dimethyl sulfoxide has led to the neutral complex iodotris(triphenylstibine)silver (1), whose structure has been established by X-ray diffraction analysis. The silver atom has distorted tetrahedral coordination. The angles SbAgSb and SbAgI equal 106.501(13)°, 109.644(13)°, 111.099(13)° и 103.063(13)°, 111.594(14)°, 114.337(14)°, the bond lengths Ag–Sb and Ag–I equal 2.7291(4), 2.7326(4), 2.8087(4) и 2.7600(4) Å.

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Литература


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