Владимир Викторович Шарутин, Ольга Константиновна Шарутина, Владислав Станиславович Сенчурин


Gold complexes [p-Tol4Sb]+[p-TolAuCl3]- (1) and [p-Tol4Sb]+[AuCl4]- (2) have been synthesized by interaction of tetra-para-tolylstibonium chloride and aurichlorohydric acid tetrahydrate in acetone. In 1 the tetra-para-tolylstibonium cations are tetrahedral (Sb-C 2.091(7)-2.097(6) Å, СSbС 106.1(3)°-112.7(3)°), the [p-TolAuCl3]- anions have square-planar structure (Au-Cl 2.286(2)-2.389(2) Å, Au-C 2.028(7) Å, ClAuCl 89.92(9)°, 92.42(9)°, 176.68(8)°, CAuCl 88.27(18)°, 89.57(18)°, 175.59(19)°). In crystal 2 the geometrical characteristics of cations (Sb-C 2.076(7)-2.097(9), СSbС 106.5(3)°-111.5(4)°) and [AuCl4]- square-planar anions (Au-Cl 2.248(3)-2.278(3) Å, ClAuCl 89.17(9)°-90.74(13)°, 177.24(16)°, 177.61(13)°) are similar to those in 1.

Ключевые слова

synthesis; structure; gold compounds; X-ray diffraction analysis

Полный текст:



Sharutin V.V., Senchurin V.S., Fastovets O.A., Pakurina A.P., Sharutina O.K. [Synthesis and Structure of Mixed-ligand Complex Compounds of Antimony [Et2NH2]4+ [SbCl2Hal4]3- [Cl]1- (Hal = I,Br) and Gold [Ph3PMe]2+ [AuCl2Br2]1- [AuHal2]1- (Hal = Cl, Br)]. Russian Journal Butlerov Communication, 2007, vol. 11, no. 2, pp. 43-48. (in Russ.)

Sharutin V.V., Senchurin V.S., Fastovets O.A., Pakurina A.P., Sharutina O.K. [Tetrafenylantimony(V) Gexachloroplatinate, Tetrachloroaurate, and Gexachlorostannate [Ph4Sb]+2 [PtCl6]2–, [Ph4Sb]+ [AuCl4]–, [Ph4Sb]+2 [SnCl6]2–: Synthesis and Crystal Structures]. Russian Journal of Coordination Chemistry, 2008, vol. 34, no. 5, pp. 367-373. DOI: 10.1134/S1070328408050096

Sharutin V.V., Senchurin V.S., Sharutina O.K., Vinokurova L.N. [Synthesis and Crystal Structure of Tetrachloroaurate butyltrifenylphosphonium [Ph3BuP]+ [AuCl4]-]. Russian Journal Butlerov Communication, 2011, vol. 27, no. 16, pp. 68-71. (in Russ.)

Sharutin V.V., Sharutina O.K., Senchurin V.S. [Synthesis and Crystal structure of acetonyltriphenylphosphonium tetrachloroaurate [Ph3PСH2C(O)CH3]+[AuCl4]–]. Russian Journal Butlerov Communication, 2014, vol. 38, no. 5, pp. 151-154. (in Russ)

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