СИНТЕЗ НАНОМАТЕРИАЛОВ С ИСПОЛЬЗОВАНИЕМ ПАВ

Д. А. Жеребцов

Аннотация


Рассмотрены методы синтеза наноматериалов с применением поверхностно-активных веществ. Приведен краткий анализ и классификация ПАВ. Одним из методов является синтез нанопористых трехмерно упорядоченных оксидных, халькогенидных или металлических наноматериалов в структуре лиотропных жидких кристаллов, формирующихся в высококонцентрированных водных растворах ПАВ. Отмечена пионерская работа 1992 г. по созданию первого мезопористого силикатного материала, послужившая инициатором широкой волны исследований в этой области. Другим методом является использование обратных мицелл ПАВ в углеводородных средах, что позволяет проводить реакции в объеме микрокапель растворов реагирующих компонентов и тем самым уменьшать размер образующихся наночастиц. Для целенаправленного использования ПАВ необходимо знание двойных и тройных диаграмм состояния вода – ПАВ и вода – масло – ПАВ, которые строятся согласно классическим представлениям физической химии о равновесии в двух- и многокомпонентных системах. В обзоре приведены наиболее подробно охарактеризованные двойные и тройные диаграммы состояния, имеющие значение для матричного синтеза. Обсуждены методы исследования диаграмм состояния. Затронуты также близко родственные системы на основе блок-сополимеров, ряд которых также может быть рассмотрен как высокомолекулярные ПАВ. Отдельно рассмотрены оксидные и оксигидроксидные наноматериалы, включающие соединения Si, Al, Ti, Zr, Hf, Nb, Ta, Mn, W, Sn, Ce и смешанных материалов, с матрицей из SiO2, на которую нанесено некоторое количество оксида другого металла: Al, V, Cr, Fe, Zr, Mo, Ni, либо металлические частицы катализаторов: Ag, Pt или Pd, полученные с применением ПАВ в процессе осаждения неорганической фазы. Приведены примеры наиболее упорядоченных мезопористых наноматериалов, образующих трехмерно периодические структуры с открытой пористостью. Предложены пути дальнейшего развития метода матричного синтеза наноматериалов с использованием ПАВ.

Ключевые слова


поверхностно-активные вещества; наноматериалы; матричный синтез

Полный текст:

PDF

Литература


P. Alexandridis, U. Olsson, B. Lindman. Self-Assembly of Amphiphilic Block Copolymers: The (E0)13(P0)30(E0)13-Water-p-Xylene System. Macromolecules (1995), 28, 7700–7710. DOI: 10.1021/ma00127a016

P. Alexandridis, U. Olsson, B. Lindman. A Record Nine Different Phases (Four Cubic, Two Hexagonal, and One Lamellar Lyotropic Liquid Crystalline and Two Micellar Solutions) in a Ternary Isothermal System of an Amphiphilic Block Copolymer and Selective Solvents (Water and Oil). Langmuir. 14. (1998) 2627–2638. DOI: 10.1021/la971117c

Allgaier J., Poppe A., Willner L., Richter D. Synthesis and Characterization of Poly[1,4-isopreneb-(ethylene oxide)] and Poly[ethylene-co-propylene-b-(ethylene oxide)] Block Copolymers. Macromolecules. 30. (1997) 1582. DOI: 10.1021/ma961311q

I. Amar-Yuli, N. Garti. Transitions induced by solubilized fat into reverse hexagonal mesophases. Colloids and Surfaces B: Biointerfaces. 43. (2005) 72–82. DOI: 10.1016/j.colsurfb.2005.03.011

R. Angelico, A. Ceglie, G. Colafemmina, F. Lopez, S. Murgia, U. Olsson, G. Palazzo. Biocompatible Lecithin Organogels: Structure and Phase Equilibria. Langmuir. 21. (2005) 140–148. DOI: 10.1021/la047974f

I.A. Ansari, N. Clarke, L.R. Hutchings, A. Pillay-Narrainen, A.E. Terry, R.L. Thompson, J.R.P. Webster. Aggregation, Adsorption, and Surface Properties of Multiply End-Functionalized Polystyrenes. Langmuir. 23. (2007) 4405–4413. DOI: 10.1021/la0635810

D.M. Antonelli, J.Y. Ying. Synthese von stabilen, hexagonal gepackten, mesoporösen Molekularsieben aus Nioboxid mittels eines neuartigen, Ligand-unterstützten Templatmechanismus. Angewandte Chemie. 108. (1996) 461–464. DOI: 10.1002/ange.19961080413

D.M. Antonelli, J.Y. Ying. Synthesis and Characterization of Hexagonally Packed Mesoporous Tantalum Oxide Molecular Sieves. Chemistry of Materials. 8. (1996) 874–881. DOI: 10.1021/cm9504697

G.S. Attard, P.N. Bartlett, N.R.B. Coleman, J.M. Elliott, J.R. Owen, J.H. Wang. Mesoporous Platinum Films from Lyotropic Liquid Crystalline Phases. Science 278, (1997) 838–840. DOI: 10.1126/science.278.5339.838

P. Bai, W. Xing, Z. Zhang, Z. Yan. Facile synthesis of thermally stable mesoporous crystalline alumina by using a novel cation–anion double hydrolysis method. Materials Letters. 59. (2005) 3128–3131. DOI: 10.1016/j.matlet.2005.05.033

G.G. Barclay, S.G. McNamee, C.K. Ober, K.I. Papathomas, D.W. Wang. The mechanical and magnetic alignment of liquid crystalline epoxy thermosets. J. Polym. Sci. Part A Polym. Chem. 30. (1992) 1845–1853. DOI: 10.1002/pola.1992.080300907

A. Bearzotti, J.M. Bertolo, P. Innocenzi, P. Falcaro, E. Traversa. Humidity sensors based on mesoporous silica thin films synthesized by block copolymers. J. of the European Ceramic Society. 24. (2004) 1969–1972. DOI: 10.1016/s0955-2219(03)00521-1

Berejnov V., Cabuil V., Perzynski R., Raikher Yu., Lysenko S., Sdobnov V. Lyotropic nematogenic system potassium laurate-1-decanol-water: Method of synthesis and study of phase diagrams. Crystallography Reports, V. 45, Nо. 3. (2000), pp. 493–500. DOI: 10.1134/1.171224

K. Beyer. Phase Structures, Water Binding, and Molecular Dynamics in Liquid Crystalline and Frozen States of the System Triton X-100-D2O. J. of Colloid and Interface Science. V. 86. No. 1. (1982) 73–89. DOI: 10.1016/0021-9797(82)90042-x

A. Bhaumik. Mesoporous titanium phosphates and related molecular sieves: Synthesis, characterization and applications. Proc. Indian Acad. Sci. (Chem. Sci.). V. 114, Nо. 4. (2002) 451–460. DOI: 10.1007/bf02703834

J.L. Blin, L. Gigot, A. Leonard, B.L. Su. Mesoporous zirconium oxides: an investigation of physico-chemical synthesis parameters. Studies in Surface Science and Catalysis. V. 141. (2002) 257–264. DOI: 10.1016/s0167-2991(02)80550-x

J.L. Blin, J. Grignard, K. Zimny, M.J. Steb. Investigation of the C16(EO)10/decane/water system for the design of porous silica materials. Colloids and Surfaces A: Physicochem. Eng. Aspects. 308. (2007) 71–78. DOI: 10.1016/j.colsurfa.2007.05.031

N. Boden, J. Clements, K.W. Jolley, D. Parker, M.H. Smith. Nematic–lamellar tricritical behavior and structure of the lamellar phase in the ammonium pentadecafluorooctanoate (APFO)/water system. J. Chem. Phys. 93. (1990) 9096–9105. DOI: 10.1063/1.459200

J. Briggs, H. Chung, M. Caffrey. The Temperature-Composition Phase Diagram and Mesophase Structure Characterization of the Monoolein. Water System. J. Phys. II France. 1996. Nо. 6. pp. 723–751. DOI: 10.1051/jp2:1996208

L.M. Bronstein, D.M. Chernyshov, G.I. Timofeeva, L.V. Dubrovina, P.M. Valetsky, A.R. Khokhlov. The Hybrids of Polystyrene-block-Poly(ethylene Oxide) Micelles and Sodium Dodecyl Sulfate in Aqueous Solutions: Interaction with Rh Ions and Rh Nanoparticle Formation. J. Coll. Interf. Sci. V. 230(1) (2000) pp. 140–149. DOI: 10.1006/jcis.2000.7085

S. Burauer, T. Sachert, T. Sottmann, R. Strey. On microemulsion phase behavior and the monomeric solubility of surfactant. Phys. Chem. Chem. Phys. No. 1. (1999) 4299–4306. DOI: 10.1039/a903542g

J. Cejka. Organized mesoporous alumina: synthesis, structure and potential in catalysis. Applied Catalysis A: General. 254. (2003) 327–338. DOI: 10.1016/s0926-860x(03)00478-2

Y.-T. Chan, H.-P. Lin, C.-Y. Moua, S.-T. Liu. Ia3d Cubic mesoporous silicas using EO17MA23 diblock copolymers made from ATRP. Chem. Commun. (2002) 2878–2879. DOI: 10.1039/b208599m

H.-R. Chen, J.-L. Shi, W.-H. Zhang, M.-L. Ruan, D.-S. Yan. Preparation and characterization of manganese oxide confined within ordered porous zirconium oxide channels. Microporous and Mesoporous Materials. 47. (2001) 173–178. DOI: 10.1016/s1387-1811(01)00373-0

P. Concepcion, M.T. Navarro, T. Blasco, J.M.L. Nieto, B. Panzacchi1, F. Rey. Vanadium oxide supported on mesoporous Al2O3. Preparation, characterization and reactivity. Catalysis Today. 96. (2004) 179–186. DOI: 10.1016/s0920-5861(04)00376-1

N. Cruise, K. Jansson, K. Holmberg. Mesoporous Alumina Made from a Bicontinuous Liquid Crystalline Phase. J. of Colloid and Interface Science. 241. (2001) 527–529. DOI: 10.1006/jcis.2001.7811

D.A. Hajduk, S. M. Gruner, P. Rangarajan, R.A. Register, L.J. Fetters, C. Honeker, R.J. Albalak, E.L. Thomas. Observation of a Reversible Thermotropic Order-Order Transition in a Diblock Copolymer. Mucromolecules. 27. (1994) 490–501. DOI: 10.1021/ma00080a024

M. Daoud, C.E. Williams (Eds.); Soft Matter Physics, Springer-Verlag Berlin, Germany, 1999.

H.T. Davis. Factors determining emulsion type: hydrophile-lipophile balance and beyond. Colloids and Surfaces A: Physicochemical and Engineering Aspects 91(1994) 9–24. DOI: 10.1016/0927-7757(94)02929-6

Y. Deng, R.N. Young, A.J. Ryan, J.P.A. Fairclough, A.I. Norman, R.D. Tack. Bulk morphology and micellization of poly(diene)–poly(ethylene oxide) diblock copolymers in water. Polymer. 43. (2002) 7155–7160. DOI: 10.1016/s0032-3861(02)00457-3

P. Du, M. Li, K. Douki, X. Li, C.B.W. Garcia, A. Jain, D.-M. Smilgies, L.J. Fetters, S.M. Gruner, U. Wiesner, C.K. Ober. Additive-driven phase-selective chemistry in block copolymer thin films: the convergence of top-down and bottom-up approaches. Adv. Mater. V. 16(12). (2004) 953–957. DOI: 10.1002/adma.200306189

M.A. Ecormier, A.F. Lee, K. Wilson. High activity, templated mesoporous SO4/ZrO2/HMS catalysts with controlled acid site density for a-pinene isomerisation. Microporous and Mesoporous Materials. 80. (2005) 301–310. DOI: 10.1016/j.micromeso.2005.01.007

K.J. Edler, T. Brennan, S.J. Roser, S. Mann, R.M. Richardson. Formation of CTAB-templated mesophase silicate films from acidic solutions. Microporous and Mesoporous Materials. 62. (2003) 165–175. DOI: 10.1016/s1387-1811(03)00402-5

H.M. El-Laithy. Preparation and Physicochemical Characterization of Dioctyl Sodium Sulfosuccinate (Aerosol OT) Microemulsion for Oral Drug Delivery. AAPS PharmSciTech. 2003. No. 4 (1) Article 11. P.1–10. DOI: 10.1208/pt040111

S.A. El-Safty. Sorption and diffusion of phenols onto well-defined ordered nanoporous monolithic silicas. J. of Colloid and Interface Science. 260. (2003) 184–194. DOI: 10.1016/s0021-9797(02)00212-6

[Esc00] J.I. Escalante, H. Hoffmann. Non-linear rheology and flow-induced transition of a lamellar-to-vesicle phase in ternary systems of alkyldimethyl oxide/alcohol/water. Rheol. Acta. V. 39. (2000) 209–214. DOI: 10.1007/s003970000085

Y.-Y. Fahn, A.-C. Su, P. Shen. Towerlike SBA-15: Base and (10)-Specific Coalescence of a Silicate-Encased Hexagonal Mesophase Tailored by Nonionic Triblock Copolymers. Langmuir. 21. (2005) 431–436. DOI: 10.1021/la0362021

F. Farzaneh, E. Zamanifar, C.D. Williams. V-MCM-41 as selective catalyst for epoxidation of olefins and trans-2-hexene-1-ol. J. of Molecular Catalysis A: Chemical. 218. (2004) 203–209. DOI: 10.1016/j.molcata.2004.03.046

P. Feng, X. Bu, G.D. Stucky, D.J. Pine. Monolithic Mesoporous Silica Templated by Microemulsion Liquid Crystals. J. Am. Chem. Soc. 2000, No. 122, pp. 994–995. DOI: 10.1021/ja992921j

P. Fernandez, V. Andre, J. Rieger, A. Kuhnle. Nano-emulsion formation by emulsion phase inversion. Colloids and Surfaces A: Physicochem. Eng. Aspects. 251. (2004) 53–58. DOI: 10.1016/j.colsurfa.2004.09.029

A.M. Figueredo Neto, L.Q. Amaral. Study of Type I Lyomesophases by X-ray Diffraction. Mol. Cryst. Liq. Cryst. 74. (1981) 109–119.

A.C. Finnefrock, R. Ulrich, G.E.S. Toombes, S.M. Gruner, U. Wiesner. The Plumber’s Nightmare: A New Morphology in Block Copolymer-Ceramic Nanocomposites and Mesoporous Aluminosilicates. J. Am. Chem. Soc. 125. (2003) 13084–13093. DOI: 10.1021/ja0355170

K. Fontell. Cubic phases in surfactant and surfactant-like lipid systems. Colloid Polym. Sci. V. 268. (1990) 264–285. DOI: 10.1007/bf01490251

L.-D. Gao, Y. Le, J.-X. Wang, J.-F. Chen. Preparation and characterization of titania nanotubes with mesostructured walls. Materials Letters. 60. (2006) 3882–3886. DOI: 10.1016/j.matlet.2006.03.133

C.B.W. Garcia, Y. Zhang, S. Mahajan, F.J. DiSalvo, U. Wiesner. Self-Assembly Approach toward Magnetic Silica-Type Nanoparticles of Different Shapes from Reverse Block Copolymer Mesophases. J. Am. Chem. Soc. 125. (2003) 13310–13311. DOI: 10.1021/ja037116q

C.G. Goltner, B. Berton, E. Kramer, M. Antonietti. Nanoporous Silicas by Casting the Aggregates of Amphiphilic Block Copolymers: The Transition from Cylinders to Lamellae and Vesicles. Adv. Mater. V. 11. No. 5. (1999) 395–398. DOI: 10.1002/(sici)1521-4095(199903)11:5<395::aidadma395> 3.3.co;2-5

V. Gonzalez-Pena, I. Diaz, C. Marquez-Alvarez, E. Sastre, J. Perez-Pariente. Thermally stable mesoporous alumina synthesized with non-ionic surfactants in the presence of amines. Microporous and Mesoporous Materials. 44–45. (2001) 203–210. DOI: 10.1016/s1387-1811(01)00185-8

P. Gopalan, Y. Zhang, X. Li, U. Wiesner, C. K. Ober, Liquid Crystalline Rod-Coil Block Copolymers by Stable Free Radical Polymerization: Synthesis, morphology, and rheology. Macromolecules. 36. (2003) 3357–3364. DOI: 10.1021/ma021573u

I. Grillo. Small-angle neutron scattering study of a world-wide known emulsion: Le Pastis. Colloids and Surfaces A: Physicochem. Eng. Aspects. 225. (2003) 153–160. DOI: 10.1016/s0927-7757(03)00331-5

P. Guenoun, H. T. Davis, H. A. Doumaux, A. Maldonado, J. W. Mays, Y. Talmon, N. Taulier, M. Tirrell, W. Urbach, Y. Zheng. Polyelectrolyte Micelles: Self-Diffusion and Electron Microscopy Studies. Langmuir. 16. (2000) 4436–4440. DOI: 10.1021/la991036b

O.Y. Gutierrez, D. Valencia, G.A. Fuentes, T. Klimova. Mo and NiMo catalysts supported on SBA-15 modified by grafted ZrO2 species: Synthesis, characterization and evaluation in 4,6-dimethyldibenzothiophene hydrodesulfurization. J. of Catalysis. 249. (2007) 140–153. DOI: 10.1016/j.jcat.2007.04.014

J. Harting, M.J. Harvey, J. Chin, P.V. Coveney. Detection and tracking of defects in the gyroid mesophase. Computer Physics Communications. 165. (2005) 97–109. DOI: 10.1016/j.cpc.2004.10.001

M. Harms, S. Mackeben, C.C. Muller-Goymann. Thermotropic transition structures in the ternary system lecithin/isopropyl myristate/water. Colloids and Surfaces A: Physicochem. Eng. Aspects. 259. (2005) 81–87. DOI: 10.1016/j.colsurfa.2005.02.013

C.-H. Hsu, H.-P. Lin, C.-Y. Tang, C.-Y. Lin. Synthesis of mesoporous silicas with different pore sizes using PEO polymers via hydrothermal treatment: A direct template for mesoporous carbon. Materials Chemistry and Physics. 100. (2006) 112–116. DOI: 10.1016/j.matchemphys.2005.12.015

Y.-Y. Huang, T.J. McCarthy, W.M.H. Sachtler. Preparation and catalytic testing of mesoporous sulfated zirconium dioxide with partially tetragonal wall structure. Applied Catalysis A: General. 148. (1996) 135–154. DOI: 10.1016/s0926-860x(96)00223-2

D.A. Huse, S. Leibler. Are sponge phases of membranes experimental Gauge-Higgs systems? Phys. Rev. Lett. 66(4). (1991) 437–440. DOI: 10.1103/physrevlett.66.437

V. Idakiev, L. Ilieva, D. Andreeva, J.L. Blin, L. Gigot, B.L. Su. Complete benzene oxidation over gold-vanadia catalysts supported on nanostructured mesoporous titania and zirconia. Applied Catalysis A: General. 243. (2003) 25–39. DOI: 10.1016/s0926-860x(02)00534-3

V. Idakiev, T. Tabakova, A. Naydenov, Z.-Y. Yuan, B.-L. Su. Gold catalysts supported on mesoporous zirconia for low-temperature water–gas shift reaction. Applied Catalysis B: Environmental. 63. (2006) 178–186. DOI: 10.1016/j.apcatb.2005.10.007

S. Inagaki, S. Guan, Y. Fukushima, T. Ohsuna, O. Terasaki. Novel Mesoporous Materials with a Uniform Distribution of Organic Groups and Inorganic Oxide in Their Frameworks. J. Am. Chem. Soc. 121. (1999) 9611–9614. DOI: 10.1021/ja9916658

P. Innocenzi, A. Martucci, M. Guglielmi, A. Bearzotti, E. Traversa. Electrical and structural characterization of mesoporous silica thin film as humidity sensors. Sensors and Actuators B. 76. (2001) 299–303. DOI: 10.1016/s0925-4005(01)00590-1

A. Jain, S. Rogojevic, S. Ponoth, N. Agarwal, I. Matthew, W.N. Gill, P. Persans, M. Tomozawa, J.L. Plawsky, E. Simonyi. Porous silica materials as low-k dielectrics for electronic and optical interconnects. Thin Solid Films. 398–399. (2001) 513–522. DOI: 10.1016/s0040-6090(01)01311-6

A. Jain, U. Wiesner. Silica-Type Mesostructures from Block Copolymer Phases: Formation Mechanism and Generalization to the Dense Nanoparticle Regime. Macromolecules. 37(15). (2004) 5665–5670. DOI: 10.1021/ma0359786

A. Jain, G. Toombes, L. Hall, S. Mahajan, C. Garcia, W. Probst, S. Gruner, U. Wiesner. Direct Access to Bicontinuous skeletal Inorganic Plumber’s Nightmare networks from block copolymers. Angew. Chem. Int. Ed. V. 44. (2005) 1226–1229. DOI: 10.1002/anie.200461156

A. Johansson, T. Drakenberg. Proton and Deuteron Magnetic Resonance Studies of Lamellar Lyotropic Mesophases. Molecular Crystals and Liquid Crystals. V. 14. (1971) 23–48. DOI: 10.1080/15421407108083555

K.W. Jolley, N. Boden, D. Parker, J.R. Henderson. Nature of the liquid crystalline phase transitions in the cesium pentadecafluorooctanoate–water system: The nematic-to-smectic-A transition. Phys. Rev. E. V. 65. (2002) 41713. DOI: 10.1103/physreve.65.041713

S.D. Junior, C.A. Kuhnen, G.R. Ouriques. Theoretical and experimental studies of the aggregation number in the ammonium perfluorooctanoate/water binary mixture. J. of Molecular Liquids. 123. (2006) 110–117. DOI: 10.1016/j.molliq.2005.02.006

M.P. Kapoor, A. Raj, Y. Matsumura. Methanol decomposition over palladium supported mesoporous CeO2-ZrO2 mixed oxides. Microporous and Mesoporous Materials. 44–45. (2001) 565–572. DOI: 10.1016/s1387-1811(01)00235-9

M.P. Kapoor, N. Setoyama, Q. Yang, M. Ohashi, S. Inagaki. Oligomeric Polymer Surfactant Driven Self-Assembly of Phenylene-Bridged Mesoporous Materials and Their Physicochemical Properties. Langmuir. 21. (2005) 443–449. DOI: 10.1021/la0482249

T. Kato. Self-Assembly of Phase-Segregated Liquid Crystal Structures. Science. V. 295. (2002) 2414–2418. DOI: 10.1126/science.1070967

P. Kim, Y. Kim, H. Kim, I.K. Song, J. Yi. Synthesis and characterization of mesoporous alumina with nickel incorporated for use in the partial oxidation of methane into synthesis gas. Applied Catalysis A: General. 272. (2004) 157–166. DOI: 10.1016/j.apcata.2004.05.055

A. Kitiyanan, S. Ngamsinlapasathian, S. Pavasupree, S. Yoshikawa. The preparation and characterization of nanostructured TiO2–ZrO2 mixed oxide electrode for efficient dye-sensitized solar cells. J. of Solid State Chemistry. 178. (2005) 1044–1048. DOI: 10.1016/j.jssc.2004.12.043

T. Klimova, M.L. Rojas, P. Castillo, R. Cuevas, J. Ramirez. Characterization of Al2O3-ZrO2 mixed oxide catalytic supports prepared by the sol-gel method. Microporous and Mesoporous Materials. 20. (1998) 293–306. DOI: 10.1016/s1387-1811(97)00024-3

M. Klotz, A. Ayral, C. Guizard, L. Cot. Synthesis conditions for hexagonal mesoporous silica layers. J. Mater. Chem. 10. (2000) 663–669. DOI: 10.1039/a906181i

D. Konjhodzic, S. Schroter, F. Marlow. Ultra-low refractive index mesoporous substrates for waveguide structures. Phys. Status Solidi A. V. 204. No. 11. (2007) 3676–3688. DOI: 10.1002/pssa.200776405

J.P.F. Lagerwall, G. Scalia. A new era for liquid crystal research: Applications of liquid crystals in soft matter nano-, bio- and microtechnology. Current Applied Physics. 12. (2012) 1387–1412. DOI: 10.1016/j.cap.2012.03.019

Y.-M. Lam, N. Grigorieff, G. Goldbeck-Wood. Direct visualisation of micelles of Pluronic block copolymers in aqueous solution by cryo-TEM. Phys. Chem. Chem. Phys. V. 1 (1999) 3331–3334. DOI: 10.1039/a902369k

K. Lazar, G. Pal-Borbely, A. Szegedi, H.K. Beyer. Coordination and oxidation states of iron incorporated into MCM-41. Studies in Surface Science and Catalysis. V. 142. Part 2. (2002) 1347–1354. DOI: 10.1016/s0167-2991(02)80299-3

H.C. Lee, H.J. Kim, C.H. Rhee, K.H. Lee, J. S. Lee, S.H. Chung. Synthesis of nanostructured c-alumina with a cationic surfactant and controlled amounts of water. Microporous and Mesoporous Materials. 79. (2005) 61–68. DOI: 10.1016/j.micromeso.2004.10.021

L. Leibler. Theory of Microphase Separation in Block Copolymers. Macromolecules. 13. (1980) 1602–1617. DOI: 10.1021/ma60078a047

J.K. Li, S. Zou, D.A. Rider, I. Manners, G.C. Walker. Differential Conductivity in Self-Assembled Nanodomains of a Diblock Copolymer Using Polystyrene-block-Poly(ferrocenylethylmethylsilane). Adv. Mater. 20. (2008) 1989–1993. DOI: 10.1002/adma.200702796

Recent Advances in Nano- and Macroscale Control of Hexagonal, Mesoporous Materials. M. Linden, S. Schacht, F. Schuth, A. Steel, K.K. Unger. J. of Porous Materials. 5. (1998) 177–193. DOI: 10.1023/a:1009666019428

G.-L. Lin, Y.-H. Tsai, H.-P. Lin, C.-Y. Tang, C.-Y. Lin. Synthesis of Mesoporous Silica Helical Fibers Using a Catanionic-Neutral Ternary Surfactant in a Highly Dilute Silica Solution: Biomimetic Silicification. Langmuir. 23. (2007) 4115–4119. DOI: 10.1021/la070154t

Y.-H. Liu, H.-P. Lin, C.-Y. Mou. One-Step Grafting of Al2O3 onto Acid-Made Mesoporous Silica. J. of the Chinese Chemical Society. 52. (2005) 717–720. DOI: 10.1002/jccs.200500100

S. Liu, S. Huang, L. Guan, J. Li, N. Zhao, W. Wei, Y. Sun. Preparation of a novel mesoporous solid base Na–ZrO2 with ultra high thermal stability. Microporous and Mesoporous Materials. 102. (2007) 304–309. DOI: 10.1016/j.micromeso.2006.12.052

S.G. Liu, H. Wang, J.P. Li, N. Zhao, W. Wei, Y.H. Sun. A facile route to synthesize mesoporous zirconia with ultra high thermal stability. Materials Research Bulletin. 42. (2007) 171–176. DOI: 10.1016/j.materresbull.2006.04.035

M. Lukaschek, D.A. Grabowski, C. Schmidt. Shear-induced alignment of a hexagonal lyotropic liquid crystal as studied by rheo-NMR. Langmuir. 11. (1995) 3590–3594. DOI: 10.1021/la00009a050

S. Mahajan, S. Renker, P. Simon, J. Gutmann, A. Jain, S. Gruner, L. Fetters, G. Coates, U. Wiesner. Synthesis and characterization of amphiphilic poly(ethylene oxide)-block-poly(hexyl methacrylate) copolymers. Macromolecular Chemistry and Physics. 204(8). (2003) 1047–1055. DOI: 10.1002/macp.200390084

S. Manit, R.A. Weiss, S.F. Hahn, C.E. Williams, M.E. Cantino, L.H. Khairallah. Microstructure of block copolymers of polystyrene and poly(ethylene-alt-propylene) Polymer. V. 39 No. 10. (1998) 2023–2033. DOI: 10.1016/s0032-3861(97)00487-4

B.J. Melde, B.T. Holland, C.F. Blanford, A. Stein. Mesoporous Sieves with Unified Hybrid Inorganic/Organic Frameworks. Chem. Mater. 11. (1999) 3302–3308. DOI: 10.1021/cm9903935

V. Meynen, P. Cool, E.F. Vansant. Synthesis of siliceous materials with micro- and mesoporosity. Microporous and Mesoporous Materials. 104. (2007) 26–38. DOI: 10.1016/j.micromeso.2006.12.003

Mitchell D.J., Tiddy G.J.T., Waring L., Bostock T., McDonald M.P. Phase behaviour of polyoxyethylene surfactants with water. Mesophase structures and partial miscibility (cloud points). J. Chem. Soc., Faraday Trans. V. 79. (1983) 975–1000. DOI: 10.1039/f19837900975

I. Molinero, M.L. Sierra, E. Rodenas. A Phase Diagram of the N-Cetylpiridinium Chloride/1-BuOH/Water Ternary System. J. Colloid Interface Sci. V. 188(2). (1997) 239–242. DOI: 10.1006/jcis.1997.4757

X. Mulet, B.J. Boyd, C.J. Drummond. Advances in drug delivery and medical imaging using colloidal lyotropic liquid crystalline dispersions. Journal of Colloid and Interface Science. 393. (2013) 1–20. DOI: 10.1016/j.jcis.2012.10.014

J.A. Muller, R.S. Stein, H.H. Winter. Rotation of liquid crystalline macromolecules in shear flow and shear-induced periodic orientation patterns. Rheol. Acta. V. 35. (1996), pp. 160–167. DOI: 10.1007/bf00396043

S.P. Naik, W. Fan, M. Ogura, T. Okubo. Phase transformation in mesoporous silica films induced by the degradation of organic moiety. J. Porous. Mater. 13. (2006) 303–306. DOI: 10.1007/s10934-006-8021-6

A. Nesrullajev, N. Kazanci. Effect of the inorganic salt on the electrical conductivity characteristics of lyotropic nematics. Czechoslovak Journal of Physics. V. 48. No. 12. (1998) 1607–1613. DOI: 10.1023/a:1022827008647

F. Nilsson, O. Soderman, I. Johansson. Physical-Chemical Properties of the n-Octyl-β-DGlucoside/Water System. A Phase Diagram, Self-Diffusion NMR, and SAXS Study. Langmuir. 12. (1996) 902–908. DOI: 10.1021/la950602+

G. Pacheco, E. Zhao, E.D. Valdes, A. Garcia, J.J. Fripiat. Microporous zirconia from anionic and neutral surfactants. Microporous and Mesoporous Materials. 32. (1999) 175–188. DOI: 10.1016/s1387-1811(99)00105-5

V.I. Parvulescu, V. Parvulescu, U. Endruschat, Ch.W. Lehmann, P. Grange, G. Poncelet, H. Bonnemann. Preparation and characterization of mesoporous zirconium oxide. Part 2. Microporous and Mesoporous Materials. 44–45. (2001) 221–226. DOI: 10.1016/s1387-1811(01)00187-1

S. Pautot, B.J. Frisken, J. Cheng, X.S. Xie, D.A. Weitz. Spontaneous Formation of Lipid Structures at Oil-Water-Lipid Interfaces. Langmuir. 2003. No. 19(24), pp. 10281–10287. DOI: 10.1021/la034532f

P. Photinos, A. Saupe. Measurements of the conductivity and relaxation times for the micellar nematic phase of the system ammonium perfluorononanoate/H2O. J. Chem. Phys. V.85(12) (1986) 7467–7471. DOI: 10.1063/1.451335

L. Powers, P.S. Pershan. Monodomain samples of dipalmitoyl phosphatidylcholine with varying concentrations of water and other ingredients. Biophys. J. V.20. (1977), p. 137. DOI: 10.1016/s0006-3495(77)85540-9

Q. Sheng, Y. Cong, S. Yuan, J. Zhang, M. Anpo. Synthesis of bi-porous TiO2 with crystalline framework using a double surfactant system. Microporous and Mesoporous Materials. 95. (2006) 220–225. DOI: 10.1016/j.micromeso.2006.05.033

Raman I.A.B., Suhaimi H., Tiddy G.J.T. Formation of microemulsions with palm-based oils stabilized by a non-ionic surfactant. J. of Oil Palm Research. V. 15. No. 2. (2003) 50–61.

J.C. Ray, K.-S. You, J.-W. Ahn, W.-S. Ahn. Mesoporous alumina (I): Comparison of synthesis schemes using anionic, cationic, and non-ionic surfactants. Microporous and Mesoporous Materials. 100. (2007) 183–190. DOI: 10.1016/j.micromeso.2006.10.036

T.-Z. Ren, Z.-Y. Yuan, B.-L. Su. Surfactant-assisted preparation of hollow microspheres of mesoporous TiO2. Chemical Physics Letters. 374. (2003) 170–175. DOI: 10.1016/s0009-2614(03)00722-x

S. Renker, S. Mahajan, D.T. Babski, I. Schnell, A. Jain, J. Gutmann, Y. Zhang, S.M. Gruner, H.W. Spiess, U. Wiesner. Nanostructure and Shape Control in Polymer-Ceramic Hybrids from Poly(ethylene oxide)-block-Poly(hexylmethacrylate) and Aluminosilicates Derived from Them. Macromol. Chem. Phys. 205. (2004) 1021–1030. DOI: 10.1002/macp.200300249

V.N. Romannikov, V.B. Fenelonov, E.A. Paukshtis, A.Yu. Derevyankin, V.I. Zaikovskii. Mesoporous basic zirconium sulfate: structure, acidic properties and catalytic behaviour. Microporous and Mesoporous Materials. 21. (1998) 41l–419. DOI: 10.1016/s1387-1811(98)00063-8

J. Ruokolainen, R. Makinen, M. Torkkeli, T. Makela, R. Serimaa, G. ten Brinke, O. Ikkala. Switching Supramolecular Polymeric Materials with Multiple Length Scales. Science. V. 280. (1998), pp. 557–560. DOI: 10.1126/science.280.5363.557

A. Samakande, P.C. Hartmann, R.D. Sanderson. Synthesis and characterization of new cationic quaternary ammonium polymerizable surfactants. J. of Colloid and Interface Science. 296. (2006) 316–323. DOI: 10.1016/j.jcis.2005.09.005

J.G. Santiesteban, D.C. Calabro, C.D. Chang, J.C. Vartuli, T.J. Fiebig, R.D. Bastian. The Role of Platinum in Hexane Isomerization over Pt/FeOy/WOx /ZrO2. J. of Catalysis. V. 202. (2001) 25–33. DOI: 10.1006/jcat.2001.3229

E.P. dos Santos, M.S. Tokumoto, G. Surendran, H. Remita, C. Bourgaux, P. Dieudonne, E. Prouzet, L. Ramos. Existence and Stability of New Nanoreactors: Highly Swollen Hexagonal Liquid Crystals. Langmuir. 21. (2005) 4362–4369. DOI: 10.1021/la047092g

V.Schädler, J. Spickermann, H.-J. Räder, U. Wiesner. Synthesis and Characterization of a,w-Zwitterionic Block copolymers of Styrene and Isoprene. Macromolecules. 29. (1996) 4865–4870. DOI: 10.1021/ma951894o

J. Sekulic, A. Magraso, J.E. ten Elshof, D.H.A. Blank. Influence of ZrO2 addition on microstructure and liquid permeability of mesoporous TiO2 membranes. Microporous and Mesoporous Materials. 72. (2004) 49–57. DOI: 10.1016/j.micromeso.2004.04.017

T. Seki, M. Onaka. Elucidation of basic properties of mesoporous alumina through the temperature-programmed desorption of carbon dioxide and heterogeneous basic catalysis of mesoporous alumina for the Knoevenagel reaction in supercritical CO2. J. of Molecular Catalysis A: Chemical. 263. (2007) 115–120. DOI: 10.1016/j.molcata.2006.08.049

Y. Shao, L. Wang, J. Zhang, M. Anpo. Synthesis and characterization of high hydrothermally stable Cr-MCM-48. Microporous and Mesoporous Materials. 109. (2008) 271–277. DOI: 10.1016/j.micromeso.2007.05.001

L. Sicard, P.L. Llewellyn, J. Patarin, F. Kolenda. Investigation of the mechanism of the surfactant removal from a mesoporous alumina prepared in the presence of sodium dodecylsulfate. Microporous and Mesoporous Materials. 44–45. (2001) 195–201. DOI: 10.1016/s1387-1811(01)00184-6

Small D. The physical chemistry of lipids: from alkanes to phospholipids. Plenum Press, New York (1986).

S.S. Soni, G. Brotons, M. Bellour, T. Narayanan, A. Gibaud. Quantitative SAXS Analysis of the P123/Water/Ethanol Ternary Phase Diagram. J. Phys. Chem. B. 110. (2006) 15157–15165. DOI: 10.1021/jp062159p

Y.W. Suh, H.-K. Rhee Synthesis of Stable Mesostructured Zirconia: Tween Surfactant and Controlled Template Removal. Korean J. Chem. Eng. – 2003. No. 20(1), pp. 65–70. DOI: 10.1007/bf02697186

G. Surendran, M.S. Tokumoto, E.P. dos Santos, H. Remita, L. Ramos, P.J. Kooyman, C.V. Santilli, C. Bourgaux, P. Dieudonne, E. Prouzet. Highly Swollen Liquid Crystals as New Reactors for the Synthesis of Nanomaterials. Chem. Mater. 2005. No. 17, pp. 1505–1514. DOI: 10.1021/cm0484495

Y. Suzuki, N. Mizoshita, K. Hanabusab, T. Kato. Homeotropically oriented nematic physical gels for electrooptical materials. J. Mater. Chem., 13. (2003) 2870–2874. DOI: 10.1039/b308098f

P. Tang, F. Qiu, H. Zhang, Y. Yang. Morphology and phase diagram of complex block copolymers: ABC linear triblock copolymers. Phys. Rev. E. V. 69. (2004) 031803. DOI: 10.1103/physreve.69.031803

A. Tarafdar, A.B. Panda, P. Pramanik. Synthesis of ZrO2–SiO2 mesocomposite with high ZrO2 content via a novel sol–gel method. Microporous and Mesoporous Materials. 84. (2005) 223–228. DOI: 10.1016/j.micromeso.2005.05.014

M. Templin, A. Franck, A. Du Chesne, H. Leist, Y. Zhang, R. Ulrich, V. Schadler, U. Wiesner. Organically modified aluminosilicate mesostructures from block copolymer phases. Science. 278(5344). (1997) 1795–1798. DOI: 10.1126/science.278.5344.1795

D. Terribile, A. Trovarelli, J. Llorca, C. de Leitenburg, G. Dolcetti. The preparation of high surface area CeO2±ZrO2 mixed oxides by a surfactant-assisted approach. Catalysis Today. 43. (1998) 79–88. DOI: 10.1016/s0920-5861(98)00136-9

Z.-R. Tian, W. Tong, J.-Y. Wang, N.-G. Duan, V.V. Krishnan, and S.L. Suib. Manganese Oxide Mesoporous Structures: Mixed-Valent Semiconducting Catalysts. Science 276. (1997) 926–930. DOI: 10.1126/science.276.5314.926

H.L. Tidahy, S. Siffert, J.-F. Lamonier, E.A. Zhilinskaya, A. Aboukaıs, Z.-Y. Yuan, A. Vantomme, B.-L. Su, X. Canet, G. De Weireld, M. Frere, T.B. N’Guyen, J.-M. Giraudon, G. Leclercq. New Pd/hierarchical macro-mesoporous ZrO2, TiO2 and ZrO2-TiO2 catalysts for VOCs total oxidation. Applied Catalysis A: General. 310. (2006) 61–69. DOI: 10.1016/j.apcata.2006.05.020

S.H. Tolbert, A. Firouzi, G.D. Stucky, B.F. Chmelka. Magnetic Field Alignment of Ordered Silicate-Surfactant Composites and Mesoporous Silica Science. V. 278 (1997) 264–268. DOI: 10.1126/science.278.5336.264

M. Trau, N. Yao, E. Kim, Y. Xia, G.M. Whitesides, I.A. Aksay. Microscopic patterning of orientatedmesoscopic silica through guided growth. Nature. V. 390 (1997) 674–676. DOI: 10.1038/37764

S. Tursiloadi, H. Imai, H. Hirashima. Preparation and characterization of mesoporous titania–alumina ceramic by modified sol–gel method. J. of Non-Crystalline Solids. 350. (2004) 271–276. DOI: 10.1016/j.jnoncrysol.2004.09.010

R. Ulrich, A. Du Chesne, M. Templin, U. Wiesner. Nano-objects with controlled shape, size, and composition from block copolymer mesophases. Advanced Materials. 11(2). (1999) 141–146. DOI: 10.1002/(sici)1521-4095(199902)11:2<141::aid-adma141>3.3.co;2-i

S. Valange, A. Derouault, J. Barrault, Z. Gabelica. One-step generation of highly selective hydrogenation catalysts involving sub-nanometric Cu2O supported on mesoporous alumina: strategies to control their size and dispersion. J. of Molecular Catalysis A: Chemical. 228. (2005) 255–266. DOI: 10.1016/j.molcata.2004.09.034

A. Vargas, J.A. Montoya, C. Maldonado, I. Hernandez-Perez, D.R. Acosta, J. Morales. Textural properties of Al2O3–TiO2 mixed oxides synthesized by the aqueous sol method. Microporous and Mesoporous Materials. 74. (2004) 1–10. DOI: 10.1016/j.micromeso.2004.06.001

E. Verploegen, B. T. Dworken, M. Faught, M. Kamperman, Y. Zhang, U. Wiesner. Tuning Mechanical Properties of Block Copolymer-Aluminosilicate Hybrid Materials. Macromolecules. Rap. Comm. 28. (2007) 572–578. DOI: 10.1002/marc.200600705

Influence of Lecithin on Structure and Stability of Parenteral Fat Emulsions. Den Naturwissenschaftlichen Fakultäten der Friedrich-Alexander-Universität Erlangen-Nürnberg. Zur Erlangung des Doktorgrades vorgelegt von Christoph Wabel aus Frankfurt am Main. Tag der mündlichen Prüfung: 30.07.1998.

G. Wanka, H. Hoffmann, W. Ulbricht. Phase Diagrams and Aggregation Behavior of Poly(oxyethy1ene)-Poly(oxypropylene)-Poly(oxyethylene) Triblock Copolymers in Aqueous Solutions. Macromolecules. 27. (1994) 4145–4159. DOI: 10.1021/ma00093a016

L.-Z. Wang, J.-L. Shi, W.-H. Zhang, M.-L. Ruan, J. Yu, D.-S. Yan. Self-Organization of Ordered Silver Nanocrystal Arrays on Cubic Mesoporous Silica Surfaces. Chem. Mater. 11. (1999) 3015–3017. DOI: 10.1021/cm990228p

C.-C. Wang, J.Y. Ying. Sol-Gel Synthesis and Hydrothermal Processing of Anatase and Rutile Titania Nanocrystals. Chem. Mater. 11. (1999) 3113–3120. DOI: 10.1021/cm990180f

Z. Wang, L. Zheng, T. Inoue. Effect of sucrose on the structure of a cubic phase formed from a monoolein/water mixture. Journal of Colloid and Interface Science. 288 (2005) 638–641. DOI: 10.1016/j.jcis.2005.03.021

L. Wang, Y. Shao, J. Zhang, M. Anpo. Synthesis of MCM-48 mesoporous molecular sieve with thermal and hydrothermal stability with the aid of promoter anions. Microporous and Mesoporous Materials. 95. (2006) 17–25. DOI: 10.1016/j.micromeso.2006.04.016

N.R. Washburn, T.P. Lodge, F.S. Bates. Ternary Polymer Blends as Model Surfactant Systems. J. Phys. Chem. B. 104. (2000) 6987–6997. DOI: 10.1021/jp994230f

D.F. Evans, Wennerström. The Colloidal Domain where Physics, Chemistry, Biology and Technology Meet. VCH Publishers Inc., New York, 1994.

W. Xi-Lian, L. Jie, Y. Bao-Lin, S. De-Zhi, W. Zhong-Ni, L. Gan-Zuo. Studies on Lyotropic Liquid Crystal Formation in the Ternary Systems of a Type of New Cationic Surfactant/n-Butanol/Water by 2H Quadrupolar Splitting and X-Ray Diffraction. J. of Dispersion Science and Technology. V. 26. No. 6 (2005) 779–783. DOI: 10.1081/dis-200063101

R. Xing, S.E. Rankin. Use of the ternary phase diagram of a mixed cationic/glucopyranoside surfactant system to predict mesostructured silica synthesis. J. of Colloid and Interface Science. 316. (2007) 930–938. DOI: 10.1016/j.jcis.2007.08.019

P. Yang, D. Zhao, D.I. Margolese, B.F. Chmelka, G.D. Stucky. Block Copolymer Templating Syntheses of Mesoporous Metal Oxides with Large Ordering Lengths and Semicrystalline Framework. Chem. Mater. 11. (1999) 2813–2826. DOI: 10.1021/cm990185c

D. Yin, L. Qin, J. Liu, C. Li, Y. Jin. Gold nanoparticles deposited on mesoporous alumina for epoxidation of styrene: Effects of the surface basicity of the supports. J. of Molecular Catalysis A: Chemical. 240. (2005) 40–48. DOI: 10.1016/j.molcata.2005.06.044

S. Yuan, Q. Sheng, J. Zhang, F. Chen, M. Anpo, Q. Zhang. Synthesis of La3+ doped mesoporous titania with highly crystallized walls. Microporous and Mesoporous Materials. 79. (2005) 93–99. DOI: 10.1016/j.micromeso.2004.10.028

X.S. Zhao and G.Q. Lu. Modification of MCM-41 by Surface Silylation with Trimethylchlorosilane and Adsorption Study. J. Phys. Chem. B, 102. (1998) 1556–1561. DOI: 10.1021/jp972788m

J.-L. Zhang, W. Li, X.-K. Meng, L. Wang, L. Zhu. Synthesis of mesoporous silica membranes oriented by self-assembles of surfactants. J. of Membrane Science. 222. (2003) 219–224. DOI: 10.1016/s0376-7388(03)00292-8

Y. Zhang, X. Shi, J.M. Kim, D. Wu, Y. Sun, S. Peng. Synthesis and catalysis of nanometersized bimodal mesoporous aluminosilicate materials. Catalysis Today. 93–95. (2004) 615–618. DOI: 10.1016/j.cattod.2004.06.098

Y. Zhao, L. Xu, Y. Wang, C. Gao, D. Liu. Preparation of Ti–Si mixed oxides by sol–gel one step hydrolysis. Catalysis Today. 93–95. (2004) 583–588. DOI: 10.1016/j.cattod.2004.06.124

R. Zhao, F. Guo, Y. Hu, H. Zhao. Self-assembly synthesis of organized mesoporous alumina by precipitation method in aqueous solution. Microporous and Mesoporous Materials. 93. (2006) 212–216. DOI: 10.1016/j.micromeso.2006.02.024

X. Zhang, J. Wang, W. Wu, C. Liu, S. Qian. Preparation of amino-functionalized mesoporous silica thin films with highly ordered large pore structures. J. Sol-Gel Sci. Technol. 43. (2007) 305–311. DOI: 10.1007/s10971-007-1588-9

J. Zhang, B. Dong, L. Zheng, N. Li, X. Li. Lyotropic liquid crystalline phases formed in ternary mixtures of 1-cetyl-3-methylimidazolium bromide/p-xylene/water: A SAXS, POM, and rheology study. J. of Colloid and Interface Science. 321. (2008) 159–165. DOI: 10.1016/j.jcis.2008.01.020

Y. Zheng, Z. Lin, J.L. Zakin, Y. Talmon, H.T. Davis, L.E. Scriven. Cryo-TEM Imaging the Flow-Induced Transition from Vesicles to Threadlike Micelles. J. Phys. Chem. B. V. 104. (2000) 5263–5271. DOI: 10.1021/jp0002998

D. Zhou, P. Alexandridis, A. Khan. Self-Assembly in a Mixture of Two Poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) Copolymers in Water. J. Of Colloid and Interface Sci. V. 183. (1996) 339–350. DOI: 10.1006/jcis.1996.0555

Вылегжанина Н.Н., Зуев Ю.Ф., Миргородская А.Б., Кудрявцева Л.А. Модификация структуры микроэмульсий масло/вода гидрофобными аминами. Метод ЭПР спиновых зондов. Структура и динамика молекулярных систем. Изд. Казанский институт биохимии и биофизики КНЦ РАН. 2003. Вып. X. Ч. 2. С. 53–56. [Vylegzhanina N.N., Zuev Yu.F., Mirgorodskaya A.B., Kudryavtseva L.A. Modification of the structure of microemulsions oil / water by hydrophobic amines. EPR method of spin probes. Structure and dynamics of molecular systems. Kazan Institute of Biochemistry and Biophysics, KSC RAS, 2003, issue X, part 2, pp. 53–56. (in Russ.)]

Жеребцов Д.А. Свойства растворов, образованных водой, фурфуриловым спиртом и полиэтиленгликолевым (10) эфиром изооктилфенола. Журнал прикладной химии. 2012. Т. 85, № 4. С. 566–570. [Zherebtsov, D.A. Properties of solutions formed by water, furfuryl alcohol, and poly(ethylene glycol) (10) isooctyl phenol ether. Russian Journal of Applied Chemistry. April 2012, vol. 85, iss. 4, pp. 584–588. DOI: 10.1134/S1070427212040088]

Зуев Ю.Ф., Вылегжанина Н.Н., Хамидуллин Р.Н., Захарова Л.Я., Кудрявцева Л.А., Коновалов А.И. Структурные перестройки в супрамолекулярной каталитической системе АОТ-нонан-вода в присутствии моно- и полиэтиленгликоля. Журнал структурной химии. Приложение. 2005. Т. 46. С. 88–94. [Zuev Yu.F., Vylegzhanina N.N., Khamidullin R.N., Zakharova L.Ya., Kudryavtzeva L.A., Konovalov A.I. Structural transitions in the aot-nonane-water supramolecular catalytic system in the presence of mono-and polyethylene glycol. Journal of Structural Chemistry. January 2006, vol. 46, iss. 1, pp. S88–S95. DOI: 10.1007/s10947-006-0157-3]




DOI: http://dx.doi.org/10.14529/met190308

Ссылки

  • На текущий момент ссылки отсутствуют.